10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine)

Base Information

• Chemical Name: 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine)
• CAS No.: 1586046-68-5
• Molecular Formula: C₄₉H₄₁GaN₈
• Molecular Weight: 811.641
• Mol file: 1586046-68-5.mol

Synonyms:10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine)

Chemical Property of 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine)

There total 2 articles about 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

pyridine (110-86-1) + gallium(III) trichloride + 10-(4-azidomethylphenyl)-5,15-dimesitylcorrole → 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine) (1586046-68-5)

Guidance literature:

for 1.5h; Reflux; Darkness;

DOI:10.1021/ic402798f

Reference yield:

4-(azidomethyl)benzaldehyde (510772-10-8) + 5-(mesityl)dipyrromethane (159152-14-4) → 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine) (1586046-68-5)

Guidance literature:

Multi-step reaction with 2 steps

1: trifluoroacetic acid / dichloromethane

2: 1.5 h / Reflux; Darkness

With trifluoroacetic acid; In dichloromethane;

DOI:10.1021/ic402798f

Reference yield: 97.0%

C43H42BF2N3O3 + 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine) (1586046-68-5) → C92H83BF2GaN11O3

Guidance literature:

With copper(l) iodide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/ic402798f

upstream raw materials:

4-(azidomethyl)benzaldehyde

5-(mesityl)dipyrromethane

pyridine

Downstream raw materials:

C₈₄H₇₆BF₂GaN₁₀O₃

C₇₆H₇₁BF₂GaN₁₁O