1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane

Base Information

• Chemical Name: 1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane
• CAS No.: 1392299-85-2
• Molecular Formula: C₂₀H₂₆B₁₀N₆
• Molecular Weight: 458.577
• Mol file: 1392299-85-2.mol

Synonyms:1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane

Chemical Property of 1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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Technology Process of 1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane

There total 1 articles about 1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,7-bis(azidomethyl)-m-carborane (1392299-77-2) + phenylacetylene (536-74-3) → 1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane (1392299-85-2)

Guidance literature:

copper(II) acetate hydrate; In toluene; copper acetate hydrate (2 mol%) added to soln. of alkyne (2.06 mmol) anddiazide; stirred (room temp., 3-20 h); evapd. (vac.); residue dissolved in ethyl acetate; washed with H2O; org.layer dried over MgSO4; evapd. (vac.); crystd. from ethyl acetate/n-hep tane; elem. anal.;

DOI:10.1016/j.poly.2012.05.036

Reference yield: 90.0%

1,7-bis[(4'-phenyl-1',2',3'-triazol-1'-yl)methyl]-m-carborane (1392299-85-2) + methyl iodide (74-88-4) → 1,1'-[(m-carboran-1,7-yl)bis(methylene)]bis(3-methyl-4-phenyl-1,2,3-triazol-3-ium iodide)

Guidance literature:

In nitromethane; MeI (1.77 mmol) added to soln. of carborane (0.44 mmol) under Ar; refluxed (5-10 h); evapd. (vac.); residue washed with n-heptane and Et2O; elem. anal.;

DOI:10.1016/j.poly.2012.05.036

upstream raw materials:

1,7-bis(azidomethyl)-m-carborane

phenylacetylene