methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate

Base Information

• Chemical Name: methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate
• CAS No.: 628328-74-5
• Molecular Formula: C₂₈H₂₄O₇
• Molecular Weight: 472.494
• Mol file: 628328-74-5.mol

Synonyms:methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate

Chemical Property of methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate

There total 1 articles about methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

dimethyl sulfate (77-78-1) + 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2-hydroxy-3-methoxybenzoic acid (628328-73-4) → methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate (628328-74-5)

Guidance literature:

With sodium hydroxide; benzyltri(n-butyl)ammonium chloride; In benzene; at 20 ℃; for 3h;

DOI:10.1039/b304216m

Reference yield: 82.0%

methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate (628328-74-5) → methyl 6-[3-(1-hydroxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate (628328-75-6)

Guidance literature:

With hydrogenchloride; hydrogen; palladium on activated charcoal; In acetic acid; at 20 ℃; for 3.5h;

DOI:10.1039/b304216m

Reference yield:

methyl 6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate (628328-74-5) → 6-(8-hydroxy-5-nitroso-naphtho[2,3-d][1,3]dioxol-6-yl)-2,3-dimethoxy-benzoic acid methyl ester

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / H₂; aq. HCl / Pd/C / acetic acid / 3.5 h / 20 °C

2: K₂CO₃; i-C₅H₁₁ONO / dimethylformamide / 3.5 h / 20 °C

With hydrogenchloride; hydrogen; potassium carbonate; isopentyl nitrite; palladium on activated charcoal; In acetic acid; N,N-dimethyl-formamide;

DOI:10.1039/b304216m

upstream raw materials:

dimethyl sulfate

6-[3-(1-benzyloxy-6,7-methylenedioxynaphthyl)]-2-hydroxy-3-methoxybenzoic acid

Downstream raw materials:

methyl 6-[3-(1-hydroxy-6,7-methylenedioxynaphthyl)]-2,3-dimethoxybenzoate

(Z)-methyl 2,3-dimethoxy-6-[2-(1-methoxyimino-6,7-methylenedioxy-4-oxo-1,4-dihydronaphthyl)]benzoate

12-benzyloxy-7,8-dimethoxy-2,3-methylenedioxybenzo[c]phenanthridine

12-benzoyloxy-7,8-dimethoxy-2,3-methylenedioxybenzo[c]phenanthridin-6(5H)-one