1,6-Anhydro-4-azido-4-deoxy-2-O-(phenylmethyl)-beta-D-glucopyranose

Base Information

Chemical Name:1,6-Anhydro-4-azido-4-deoxy-2-O-(phenylmethyl)-beta-D-glucopyranose
CAS No.:145240-53-5
Molecular Formula:C₁₃H₁₅N₃O₄
Molecular Weight:277.28
Hs Code.:
DSSTox Substance ID:DTXSID801171567

Synonyms:DTXSID801171567;1,6-Anhydro-4-azido-4-deoxy-2-O-(phenylmethyl)-beta-D-glucopyranose;145240-53-5

Suppliers and Price of 1,6-Anhydro-4-azido-4-deoxy-2-O-(phenylmethyl)-beta-D-glucopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,6-Anhydro-4-azido-4-deoxy-2-O-(phenylmethyl)-beta-D-glucopyranose

Chemical Property:

XLogP3:1.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:4
Exact Mass:277.10625597
Heavy Atom Count:20
Complexity:382

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C2C(C(C(C(O1)O2)OCC3=CC=CC=C3)O)N=[N+]=[N-]
Isomeric SMILES:C1[C@@H]2[C@H]([C@@H]([C@H]([C@H](O1)O2)OCC3=CC=CC=C3)O)N=[N+]=[N-]

Technology Process of 1,6-Anhydro-4-azido-4-deoxy-2-O-(phenylmethyl)-beta-D-glucopyranose

There total 2 articles about 1,6-Anhydro-4-azido-4-deoxy-2-O-(phenylmethyl)-beta-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 33208-46-7
1,6:3,4-Dianhydro-2-O-benzyl-β-D-galactopyranose

: 145240-53-5
1,6-Anhydro-4-azido-2-O-benzyl-4-deoxy-β-D-glucopyranose

Guidance literature:: With sodium azide; ammonium chloride; In 2-methoxy-ethanol; at 110 - 120 ℃; for 25h;
DOI:10.1135/cccc20010799

Reference yield:

: 100-39-0
benzyl bromide

: 145240-53-5
1,6-Anhydro-4-azido-2-O-benzyl-4-deoxy-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran; dimethylformamide / -15 °C

1.2: tetrabutylammonium iodide / tetrahydrofuran; dimethylformamide / -15 - 20 °C

2.1: 72 percent / aq. NaN₃; ammonium chloride / 2-methoxy-ethanol / 25 h / 110 - 120 °C

With sodium azide; ammonium chloride; sodium hydride; In tetrahydrofuran; 2-methoxy-ethanol; N,N-dimethyl-formamide;
DOI:10.1135/cccc20010799