(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

Base Information

Chemical Name:(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide
CAS No.:155234-14-3
Molecular Formula:C₂₂H₃₃NO₂S
Molecular Weight:375.576
Hs Code.:

Synonyms:(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

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Chemical Property of (1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

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Technology Process of (1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

There total 7 articles about (1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 155234-11-0
C₂₂H₃₃NOS

: (1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

: 155234-14-3
(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; at -78 ℃; for 0.166667h;
DOI:10.1021/jo00083a037

Reference yield:

: 100-52-7
benzaldehyde

: 155234-14-3
(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂; tetrahydrofuran / 28 h / Ambient temperature

2: 82 percent / 85percent m-chloroperoxybenzoic acid / tetrahydrofuran / 0.17 h / -78 °C

With 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00083a037

Reference yield:

: 153336-76-6
(1S,2R,3S,4R)-3-(2,2-dimethylpropoxy)-4,7,7-trimethylbicyclo<2.2.1>heptane-2-thiol

: 155234-14-3
(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]heptane-2-sulfinic acid 1-phenyl-meth-(E)-ylideneamide

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / N-chlorosuccinimide, NH₃ / tetrahydrofuran / 0.5 h / -33 °C

2: CH₂Cl₂; tetrahydrofuran / 28 h / Ambient temperature

3: 82 percent / 85percent m-chloroperoxybenzoic acid / tetrahydrofuran / 0.17 h / -78 °C

With N-chloro-succinimide; ammonia; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00083a037