C₃₃H₄₄O₃SSe

Base Information

• Chemical Name: C₃₃H₄₄O₃SSe
• CAS No.: 933769-64-3
• Molecular Formula: C₃₃H₄₄O₃SSe
• Molecular Weight: 599.737
• Mol file: 933769-64-3.mol

Synonyms:C₃₃H₄₄O₃SSe

Chemical Property of C₃₃H₄₄O₃SSe

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₃H₄₄O₃SSe

There total 1 articles about C₃₃H₄₄O₃SSe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Phenylselenyl chloride (5707-04-0) + (E)-(1R,3aR,8S,10S,12aS)-1-Isopropyl-3a,6,10-trimethyl-8-(toluene-4-sulfonyl)-2,3,3a,4,8,9,10,11,12,12a-decahydro-1H-cyclopentacycloundecen-7-one (141434-75-5) → C33H44O3SSe (933769-64-3)

Guidance literature:

(E)-(1R,3aR,8S,10S,12aS)-1-Isopropyl-3a,6,10-trimethyl-8-(toluene-4-sulfonyl)-2,3,3a,4,8,9,10,11,12,12a-decahydro-1H-cyclopentacycloundecen-7-one; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃;

Phenylselenyl chloride; In tetrahydrofuran; at 0 ℃; Further stages.;

DOI:10.1002/anie.200603853

Reference yield:

C33H44O3SSe (933769-64-3) → C27H38O3S (933769-65-4)

Guidance literature:

With dihydrogen peroxide; In water;

DOI:10.1002/anie.200603853

Reference yield:

C33H44O3SSe (933769-64-3) → C27H40O3S

Guidance literature:

Multi-step reaction with 2 steps

1: H₂O₂ / H₂O

2: 95 percent / diisobutylaluminum hydride / -78 °C

With dihydrogen peroxide; diisobutylaluminium hydride; In water;

DOI:10.1002/anie.200603853

upstream raw materials:

Phenylselenyl chloride

(E)-(1R,3aR,8S,10S,12aS)-1-Isopropyl-3a,6,10-trimethyl-8-(toluene-4-sulfonyl)-2,3,3a,4,8,9,10,11,12,12a-decahydro-1H-cyclopentacycloundecen-7-one

Downstream raw materials:

C₂₇H₃₈O₃S