trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium

Base Information

Chemical Name:trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium
CAS No.:90791-57-4
Molecular Formula:C₅₆H₃₆Cl₆N₂O₄OsP₂
Molecular Weight:1265.78
Hs Code.:

Synonyms:trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium

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Chemical Property of trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium

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Technology Process of trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium

There total 1 articles about trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 90791-56-3
K2[Os(η4-CHBA-DCB)(O)2]*1.5 H2O

: 90791-57-4
trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium

Guidance literature:: With PPh₃; In tetrahydrofuran; trifluoroacetic acid; heating until most of THF had evapd., dissoln. in CH2Cl2; chromy. on silica gel (CH2Cl2), addn. of hexane, removing of CH2Cl2; elem. anal.;
DOI:10.1021/ja00328a028

Reference yield: 93.0%

: 90791-57-4
trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium

: 103851-28-1
[Os(C₆H₂Cl₂(NC(O)C₆H₂Cl₂O)2)(CH₂P(C₆H₅)2)2]

Guidance literature:: With C₂H₄(P(C₆H₅)2)2; In benzene; refluxing (15 min); cooling; evapn. of solvent; eluting through silica gel with excess of CH2Cl2; recrystn. (CH2Cl2/hexane); elem. anal.;
DOI:10.1021/ja00281a024

Reference yield: 86.0%

: 3978-81-2
4-tert-butylpyridine

: 90791-57-4
trans-(η4-(1,2-bis(2-hydroxy-3,5-dichlorobenzamido)-4,5-dichlorobenzene))bis(triphenylphosphine)osmium

: 110-54-3
hexane

: 90791-58-5
Os(η4-CHBA-DCB)(t-BuPy)(PPh3)*0.5(hexane)

Guidance literature:: In dichloromethane; Os complex was dissolved in CH2Cl2, ligand was added, then refluxing for 0.5 h; evapn., recrystn. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/ja00328a028