2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene

Base Information

Chemical Name:2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene
CAS No.:65113-29-3
Molecular Formula:C₃₀H₃₁P₃
Molecular Weight:484.497
Hs Code.:

Synonyms:2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene

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Chemical Property of 2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene

Chemical Property:

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Technology Process of 2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene

There total 2 articles about 2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 38023-29-9
1,2-diphenylphosphinobenzene

: 73373-21-4
bis(3-chloropropyl)phenylphosphine

: 65113-29-3
2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; Heating;
DOI:10.1021/ja00521a025

Reference yield:

: 638-21-1
phenylphosphane

: 65113-29-3
2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene

Guidance literature:: Multi-step reaction with 2 steps

1: 36 percent / n-butyllithium / hexane; tetrahydrofuran / -78 °C

2: 34 percent / n-butyllithium / hexane; tetrahydrofuran / Heating

With n-butyllithium; In tetrahydrofuran; hexane;
DOI:10.1021/ja00521a025

Reference yield: 41.0%

: 14040-11-0
tungsten hexacarbonyl

: 65113-29-3
2,6,10-triphenyl-2,6,10-triphosphabicyclo<9.4.0>pentadeca-11(1),12,14-triene

: 79190-85-5
tri(carbonyl-κC)[meso-cis-2,6,10-triphenyl-2,6,10-triphospha-κ3P-bicyclo[9.4.0]pentadeca-11(1),12,14-triene]tungsten(O)

Guidance literature:: In 1,3,5-trimethyl-benzene; heating mixt. of W(CO)6 and 1:1 mixt. of meso-cis and meso-trans ligandin degassed mesitylene at 165°C for 16 h; reaction was monitoredby IR spectroscopy;; filtered while hot; cooling to room temp.; crystn. of analytically pureproduct; elem. anal.;;