2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide

Base Information

• Chemical Name: 2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide
• CAS No.: 160066-45-5
• Molecular Formula: C₁₃H₁₁F₉O₂S
• Molecular Weight: 402.281
• Mol file: 160066-45-5.mol

Synonyms:2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide

Chemical Property of 2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide

There total 4 articles about 2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

2-perfluorobutyl-2-hydroxyethyl phenyl sulfoxide (160066-42-2) + methyl iodide (74-88-4) → 2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide (160066-45-5)

Guidance literature:

With silver(l) oxide; In N,N-dimethyl-formamide; for 6h; Ambient temperature;

DOI:10.1016/0022-1139(94)03071-5

Reference yield:

(Nonafluoro-n-butyl)epoxide (89807-87-4) → 2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide (160066-45-5)

Guidance literature:

Multi-step reaction with 3 steps

1: 82 percent / 20 h / Ambient temperature

2: 96 percent / TiCl₃, 30percent H₂O₂ / H₂O; methanol / 1.) 0 deg C, 30 min, 2.) r.t.

3: 83 percent / Ag₂O / dimethylformamide / 6 h / Ambient temperature

With titanium(III) chloride; dihydrogen peroxide; silver(l) oxide; In methanol; water; N,N-dimethyl-formamide;

DOI:10.1016/0022-1139(94)03071-5

Reference yield:

thiophenol (108-98-5) → 2-perfluorobutyl-2-methoxyethyl phenyl sulfoxide (160066-45-5)

Guidance literature:

Multi-step reaction with 3 steps

1: 82 percent / 20 h / Ambient temperature

2: 96 percent / TiCl₃, 30percent H₂O₂ / H₂O; methanol / 1.) 0 deg C, 30 min, 2.) r.t.

3: 83 percent / Ag₂O / dimethylformamide / 6 h / Ambient temperature

With titanium(III) chloride; dihydrogen peroxide; silver(l) oxide; In methanol; water; N,N-dimethyl-formamide;

DOI:10.1016/0022-1139(94)03071-5

upstream raw materials:

2-perfluorobutyl-2-hydroxyethyl phenyl sulfoxide

methyl iodide

(Nonafluoro-n-butyl)epoxide

thiophenol

Downstream raw materials:

2-perfluorobutyl-1-acetoxy-2-methoxyethyl phenyl sulfide