1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene

Base Information

• Chemical Name: 1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene
• CAS No.: 1129399-13-8
• Molecular Formula: C₁₆H₁₅F₃O₂
• Molecular Weight: 296.289
• Mol file: 1129399-13-8.mol

Synonyms:1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene

Chemical Property of 1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene

There total 1 articles about 1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

4-Iodobenzotrifluoride (455-13-0) + 3-(1-(allyloxy)prop-2-ynyloxy)prop-1-ene (102306-66-1) → 1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene (1129399-13-8)

Guidance literature:

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/adsc.200800514

Reference yield:

1-(3,3-bis(allyloxy)prop-1-ynyl)-4-(trifluoromethyl)benzene (1129399-13-8) + 3-phenyl-propenal (104-55-2) → 1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one (1129399-40-1) + 1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one (1129399-39-8) + 1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one (1129399-42-3) + 1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one (1129399-43-4)

Guidance literature:

With chloro(1,5-cyclooctadiene)rhodium(I) dimer; (S)-[(5,6),(5’,6’)-bis(ethylenedioxy)biphenyl-2,2’ diyl]bis(diphenylphosphine); at 120 ℃; for 1.5h; optical yield given as %ee; Inert atmosphere;

DOI:10.1002/adsc.200800514

upstream raw materials:

4-Iodobenzotrifluoride

3-(1-(allyloxy)prop-2-ynyloxy)prop-1-ene

Downstream raw materials:

1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one

1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one

1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one

1-(allyloxy)-6-(4-(trifluoromethyl)phenyl)-3a,4-dihydro-1H-cyclopenta[c]furan-5(3H)-one