C₂₇H₂₃BF₂N₂S₈

Base Information

• Chemical Name: C₂₇H₂₃BF₂N₂S₈
• CAS No.: 1613292-93-5
• Molecular Formula: C₂₇H₂₃BF₂N₂S₈
• Molecular Weight: 680.829
• Mol file: 1613292-93-5.mol

Synonyms:C₂₇H₂₃BF₂N₂S₈

Chemical Property of C₂₇H₂₃BF₂N₂S₈

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of C₂₇H₂₃BF₂N₂S₈

There total 2 articles about C₂₇H₂₃BF₂N₂S₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1,9-diformyl-5-phenyl-BODIPY (1613292-94-6) + (4,5-Bis-methylsulfanyl-[1,3]dithiol-2-yl)-phosphonic acid diethyl ester → C27H23BF2N2S8 (1613292-93-5)

Guidance literature:

(4,5-Bis-methylsulfanyl-[1,3]dithiol-2-yl)-phosphonic acid diethyl ester; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

1,9-diformyl-5-phenyl-BODIPY; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/c4cc02567a

Reference yield:

1,9-bisformyl-5-phenyldipyrromethane (214554-40-2) → C27H23BF2N2S8 (1613292-93-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 1 h / 90 °C

1.2: 0.5 h

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.2: 0.5 h / -78 - 20 °C / Inert atmosphere

With n-butyllithium; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; hexane; toluene; 2.1: |Horner-Wadsworth-Emmons Olefination / 2.2: |Horner-Wadsworth-Emmons Olefination;

DOI:10.1039/c4cc02567a

Reference yield:

C27H23BF2N2S8 (1613292-93-5) + tris(p-bromophenylammoniumyl) hexachloroantimonate → C27H23BF2N2S8(1+)*Cl6Sb(1-)

Guidance literature:

In dichloromethane; at 24.84 ℃;

DOI:10.1039/c4cc02567a

upstream raw materials:

1,9-diformyl-5-phenyl-BODIPY

1,9-bisformyl-5-phenyldipyrromethane