bis(9-phenyl-9-fluorenyl) peroxide

Base Information

• Chemical Name: bis(9-phenyl-9-fluorenyl) peroxide
• CAS No.: 35377-95-8
• Molecular Formula: C₃₈H₂₆O₂
• Molecular Weight: 514.623
• Mol file: 35377-95-8.mol

Synonyms:bis(9-phenyl-9-fluorenyl) peroxide

Chemical Property of bis(9-phenyl-9-fluorenyl) peroxide

Chemical Property:

Purity/Quality:

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Technology Process of bis(9-phenyl-9-fluorenyl) peroxide

There total 15 articles about bis(9-phenyl-9-fluorenyl) peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

9,9'-diphenyl-9,9'-bifluorene (59110-36-0) → bis(9-phenyl-9-fluorenyl) peroxide (35377-95-8)

Guidance literature:

With oxygen; In cyclohexane; at 60 ℃; for 2h;

DOI:10.1021/jo961321p

Reference yield: 39.0%

9-phenyl-fluoren-9-ol (25603-67-2) → bis(9-phenyl-9-fluorenyl) peroxide (35377-95-8) + 2'-hydroxy-[1,1'-biphenyl]-2-yl benzoate (123613-85-4)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; acetic acid; Ambient temperature;

Reference yield:

1,3,5-tri-tert-butyl-7-(9-phenyl-9-fluorenyl)-1,3,5-cycloheptatriene → 1,3,5-Tri-tert-butylbenzene (1460-02-2) + bis(9-phenyl-9-fluorenyl) peroxide (35377-95-8) + 1,1',3,3',5,5'-hexa-tert-butyl-7,7'-bicycloheptatriene + 1-(5-(tert-butyl)-2-hydroxyphenyl)-2,2-dimethylpropan-1-one + 1-(4-tert-Butyl-2-hydroxy-phenyl)-2,2-dimethyl-propan-1-one + 9-(tert-butylperoxy)-9-phenyl-9H-fluorene

Guidance literature:

With oxygen; In cyclohexane; at 25 ℃; for 22h; Product distribution; Equilibrium constant; Thermodynamic data; self-initiated autooxidation of a sterically crowded 1,3,5-tri-tert-butyl-7-(9-phenyl-9-fluorenyl)-1,3,5-cycloheptatriene; enthalpy and entropy of homolytic dissociation; temperature dependence of equilibrium constant of the homolysis;

DOI:10.1021/jo961321p

upstream raw materials:

9-phenyl-fluoren-9-ol

9-phenyl-fluoren-9-yl hydroperoxide

9-chloro-9-phenyl-9H-fluorene

9,9'-diphenyl-9,9'-bifluorene