10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide

Base Information

• Chemical Name: 10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide
• CAS No.: 1221262-42-5
• Molecular Formula: C₃₁H₃₆BIN₂O₄
• Molecular Weight: 638.353
• Mol file: 1221262-42-5.mol

Synonyms:10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide

Chemical Property of 10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide

There total 3 articles about 10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-(2-methoxyethoxy)prop-1-yne (31995-08-1) + 4,4-difluoro-8-(4'-iodophenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene → 10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide (1221262-42-5)

Guidance literature:

3-(2-methoxyethoxy)prop-1-yne; With ethylmagnesium bromide; In tetrahydrofuran; at 60 ℃; for 2h;

4,4-difluoro-8-(4'-iodophenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene; In tetrahydrofuran; at 60 ℃;

DOI:10.1021/jo300477p

Reference yield:

4-iodobenzoic acid chloride (1711-02-0) → 10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide (1221262-42-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dichloromethane / 72 h / 25 °C

1.2: 1 h

1.3: 25 °C

2.1: ethylmagnesium bromide / tetrahydrofuran / 2 h / 60 °C

2.2: 12 h / 25 °C

With ethylmagnesium bromide; In tetrahydrofuran; dichloromethane;

DOI:10.1021/cm503577y

Reference yield:

2,4-dimethyl-1H-pyrrole (625-82-1) → 10-(4-iodophenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide (1221262-42-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dichloromethane / 72 h / 25 °C

1.2: 1 h

1.3: 25 °C

2.1: ethylmagnesium bromide / tetrahydrofuran / 2 h / 60 °C

2.2: 12 h / 25 °C

With ethylmagnesium bromide; In tetrahydrofuran; dichloromethane;

DOI:10.1021/cm503577y

upstream raw materials:

3-(2-methoxyethoxy)prop-1-yne

4-iodobenzoic acid chloride

2,4-dimethyl-1H-pyrrole

Downstream raw materials:

[(CH₃OC₂H₄OCH₂C₂)2B(C(NC₄H(CH₃)2)2C₆H₄CHO)]

C₅₇H₅₉BN₄O₄S₂Si

10-(4-carboxyphenyl)-5,5-bis(3-(2-methoxyethoxy)prop-1-yn-1-yl)-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide

C₃₁H₃₈BN₃O₄