N,N'-Bis[2-(diphenylphosphino)benzyl]ethane-1,2-diamine

Base Information

Chemical Name:N,N'-Bis[2-(diphenylphosphino)benzyl]ethane-1,2-diamine
CAS No.:148934-67-2
Molecular Formula:C₄₀H₃₈N₂P₂
Molecular Weight:608.703
Hs Code.:
DSSTox Substance ID:DTXSID501171168
Nikkaji Number:J1.711.863C

Synonyms:SCHEMBL704404;DTXSID501171168;N,N'-Bis[2-(diphenylphosphino)benzyl]ethane-1,2-diamine;N1,N2-Bis[[2-(diphenylphosphino)phenyl]methyl]-1,2-ethanediamine;148934-67-2

Suppliers and Price of N,N'-Bis[2-(diphenylphosphino)benzyl]ethane-1,2-diamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N,N'-Bis[2-(diphenylphosphino)benzyl]ethane-1,2-diamine

Chemical Property:

XLogP3:7.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:13
Exact Mass:608.25102322
Heavy Atom Count:44
Complexity:667

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3CNCCNCC4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6

Technology Process of N,N'-Bis[2-(diphenylphosphino)benzyl]ethane-1,2-diamine

There total 2 articles about N,N'-Bis[2-(diphenylphosphino)benzyl]ethane-1,2-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 50777-76-9
(2-formylphenyl)(diphenyl)phosphine

: 107-15-3,85404-18-8
ethylenediamine

: 148934-67-2
N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine

Guidance literature:: In ethanol; for 1.5h; Reflux;
DOI:10.1016/j.inoche.2021.108719

Reference yield: 58.0%

: N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediimine

: 148934-67-2
N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c9dt00109c

Reference yield: 84.0%

: 15529-49-4,41756-81-4
dichlorotris(triphenylphosphine)ruthenium(II)

: 148934-67-2
N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine

: 67-66-3,8013-54-5
chloroform

: trans-RuCl2(PPh3)(κ3-N,N'-bis[o-(dipenylphosphino)benzylidene]-1,2-diaminoethane)*0.75(chloroform)

Guidance literature:: In dichloromethane; under N2 or in vac.; a soln. of a ligand (0.1 mmol) and Ru-contg. compd.(0.1 mmol) in CH2Cl2 was stirred at room temp. for 4 h; the solvent was removed in vac.; the residue was washed with n-hexane; column chromy. (silica gel); eluting with chloroform; removal of the solvent from the orange band; crystn. in a chloroform-hexane mixt.; elem. anal.; (31)P NMR spectra monitoring;
DOI:10.1039/b106997g