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(S)-(-)-methyl 2-(4-fluorophenyl)-3-hydroxycyclopent-1-enecarboxylate

Base Information Edit
  • Chemical Name:(S)-(-)-methyl 2-(4-fluorophenyl)-3-hydroxycyclopent-1-enecarboxylate
  • CAS No.:459174-07-3
  • Molecular Formula:C13H13FO3
  • Molecular Weight:236.243
  • Hs Code.:
  • Mol file:459174-07-3.mol
(S)-(-)-methyl 2-(4-fluorophenyl)-3-hydroxycyclopent-1-enecarboxylate

Synonyms:(S)-(-)-methyl 2-(4-fluorophenyl)-3-hydroxycyclopent-1-enecarboxylate

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Chemical Property of (S)-(-)-methyl 2-(4-fluorophenyl)-3-hydroxycyclopent-1-enecarboxylate Edit
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Technology Process of (S)-(-)-methyl 2-(4-fluorophenyl)-3-hydroxycyclopent-1-enecarboxylate

There total 8 articles about (S)-(-)-methyl 2-(4-fluorophenyl)-3-hydroxycyclopent-1-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
Multi-step reaction with 4 steps
1.1: 92 percent / potassium phosphate; palladium(II) acetate; 2-(di-tert-butylphosphino)biphenyl / dioxane / 12 h / Heating
2.1: phosphorus oxybromide; disodium hydrogenphosphate / acetonitrile / 1.5 h / 65 °C
2.2: potassium hydroxide / acetonitrile; H2O / 20 °C
3.1: 90 percent / n-tributylamine / 5percent Pd/C / N,N-dimethyl-acetamide / 12 h / 60 °C / 517.16 Torr
4.1: (R)-1-CH3-3,3-(C6H5)2-C5H7BNO; BH3*SMe3 / toluene / 2 h / -20 - -15 °C
With potassium phosphate; disodium hydrogenphosphate; tributyl-amine; dimethylsulfide borane complex; (R)-1-CH3-3,3-(C6H5)2-C5H7BNO; palladium diacetate; johnphos; phosphorus(V) oxybromide; 5percent Pd/C; In 1,4-dioxane; N,N-dimethyl acetamide; toluene; acetonitrile;
DOI:10.1021/jo025883m
Guidance literature:
Multi-step reaction with 3 steps
1.1: phosphorus oxybromide; disodium hydrogenphosphate / acetonitrile / 1.5 h / 65 °C
1.2: potassium hydroxide / acetonitrile; H2O / 20 °C
2.1: 90 percent / n-tributylamine / 5percent Pd/C / N,N-dimethyl-acetamide / 12 h / 60 °C / 517.16 Torr
3.1: (R)-1-CH3-3,3-(C6H5)2-C5H7BNO; BH3*SMe3 / toluene / 2 h / -20 - -15 °C
With disodium hydrogenphosphate; tributyl-amine; dimethylsulfide borane complex; (R)-1-CH3-3,3-(C6H5)2-C5H7BNO; phosphorus(V) oxybromide; 5percent Pd/C; In N,N-dimethyl acetamide; toluene; acetonitrile;
DOI:10.1021/jo025883m
Guidance literature:
With oxygen; caesium carbonate; (-)-sparteine; dichloro(norbornadiene)palladium(II); In toluene; tert-butyl alcohol; at 60 ℃; for 1h; under 760.051 Torr; Further Variations:; Reagents; Solvents; Temperatures; Product distribution;
DOI:10.1002/adsc.200303188
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