s-p-tolyl cyclopropanecarbothioate

Base Information

• Chemical Name: s-p-tolyl cyclopropanecarbothioate
• CAS No.: 26065-79-2
• Molecular Formula: C₁₁H₁₂OS
• Molecular Weight: 192.282
• Mol file: 26065-79-2.mol

Synonyms:s-p-tolyl cyclopropanecarbothioate

Chemical Property of s-p-tolyl cyclopropanecarbothioate

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of s-p-tolyl cyclopropanecarbothioate

There total 3 articles about s-p-tolyl cyclopropanecarbothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

→ s-p-tolyl cyclopropanecarbothioate (26065-79-2)

Guidance literature:

With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; N-ethyl-N,N-diisopropylamine; In acetonitrile; at 20 ℃; for 6h; Inert atmosphere; Glovebox; Irradiation;

Reference yield: 50.0%

cyclopropanecarboxylic acid chloride (4023-34-1) + sodium 4-methylbenzenesulfinate (824-79-3) → s-p-tolyl cyclopropanecarbothioate (26065-79-2)

Guidance literature:

With fac-tris(2-phenylpyridinato-N,C₂')iridium(III); diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; N-ethyl-N,N-diisopropylamine; In 1,2-dichloro-ethane; at 23 ℃; for 6h; Inert atmosphere; Irradiation; Sealed tube;

DOI:10.1021/acs.orglett.9b01218

Reference yield:

cyclopropanecarboxylic acid chloride (4023-34-1) + para-thiocresol (106-45-6) → s-p-tolyl cyclopropanecarbothioate (26065-79-2)

Guidance literature:

With pyridine; In diethyl ether; at 0 - 5 ℃;

DOI:10.1039/b107403m

upstream raw materials:

cyclopropanecarboxylic acid chloride

para-thiocresol

sodium 4-methylbenzenesulfinate

Downstream raw materials:

cyclopropanecarboxylic acid benzylamide