rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine

Base Information

Chemical Name:rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine
CAS No.:1430616-81-1
Molecular Formula:C₃₆H₄₂N₃P
Molecular Weight:547.723
Hs Code.:

Synonyms:rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine

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Chemical Property of rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine

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Technology Process of rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine

There total 3 articles about rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 1430616-75-3,1430723-26-4
rac-5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazole

: 16523-54-9
chlorodicyclohexylphosphane

: 1430616-81-1
rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine

Guidance literature:: rac-5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazole; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at 0 ℃; for 1.5h; Inert atmosphere;

chlorodicyclohexylphosphane; In tetrahydrofuran; hexane; at 0 - 40 ℃; for 16h; Inert atmosphere;
DOI:10.1002/ejoc.201300031

Reference yield:

: 111870-61-2
4-ethynyl-[2.2]-p-cyclophane

: 1430616-81-1
rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine

Guidance literature:: Multi-step reaction with 2 steps

1.1: ethylmagnesium bromide / diethyl ether; tetrahydrofuran / 0.25 h / 50 °C / Inert atmosphere

1.2: 20 - 50 °C / Inert atmosphere

2.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 1.5 h / 0 °C / Inert atmosphere

2.2: 16 h / 0 - 40 °C / Inert atmosphere

With ethylmagnesium bromide; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1002/ejoc.201300031

Reference yield:

: 622-37-7
Phenyl azide

: 1430616-81-1
rac-dicyclohexyl(5-(tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaen-5-yl)-1-phenyltriazol-4-yl)phosphine

Guidance literature:: Multi-step reaction with 2 steps

1.1: ethylmagnesium bromide / diethyl ether; tetrahydrofuran / 0.25 h / 50 °C / Inert atmosphere

1.2: 20 - 50 °C / Inert atmosphere

2.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 1.5 h / 0 °C / Inert atmosphere

2.2: 16 h / 0 - 40 °C / Inert atmosphere

With ethylmagnesium bromide; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1002/ejoc.201300031