[(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)]

Base Information

• Chemical Name: [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)]
• CAS No.: 32613-25-5
• Molecular Formula: C₂₄H₂₀ClOPRu
• Molecular Weight: 491.919
• Mol file: 32613-25-5.mol

Synonyms:[(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)]

Chemical Property of [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)]

There total 17 articles about [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C5H5Ru(CO)(P(C6H5)3)NO3 (348624-98-6) + bis(triphenylphosphine)iminium chloride (21050-13-5) → [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)] (32613-25-5) + bis(triphenylphosphine)iminium nitrate (38011-35-7)

Guidance literature:

In dichloromethane; 25°C, CH2Cl2; not sepd., detected by UV spectra; Kinetics;

DOI:10.1021/om000670d

Reference yield: 95.0%

sulfur (10544-50-0) + chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) → [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)] (32613-25-5)

Guidance literature:

With carbon monoxide; In toluene; a suspn. of Ru-complex and S8 in toluene was pressuried with CO (2 atm), mixt. was stirred for 8 h at 120°C, cooled, solvent was removedunder reduced pressure, extd. with CH2Cl2, concd. under N2; soln. was put on an alumina column in Et2O, washed through with Et2O followed by CH2Cl2, ppt. was eluted with acetone, solvent was removed, residue crystd. from CH2Cl2-light petroleum;

DOI:10.1039/DT9840000993

Reference yield: 91.0%

(η(5)-cyclopentadienyl)dicarbonylchlororuthenium(II) + triphenylphosphine (603-35-0) → [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)] (32613-25-5)

Guidance literature:

(η(5)-cyclopentadienyl)dicarbonylchlororuthenium(II); With trimethylamine-N-oxide; In acetonitrile; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

triphenylphosphine; In acetonitrile; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2019.120888

upstream raw materials:

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

bi(cyclopentadiene)

sodium tetraphenyl borate

n-octyne