{RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl

Base Information

Chemical Name:{RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl
CAS No.:146816-53-7
Molecular Formula:C₄₂H₇₈ClP₄Ru*Cl
Molecular Weight:878.952
Hs Code.:

{RuCl(P(CH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>11</sub>)2)3)}<sup>(1+)</sup>*Cl<sup>(1-)</sup>={RuCl(P(C<sub>2</sub>H<sub>4</sub>P(C<sub>6</sub>H<sub>11</sub>)2)3)}Cl

Synonyms:{RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl

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Chemical Property of {RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl

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Technology Process of {RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl

There total 1 articles about {RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 146337-60-2
tris(2-(dicyclohexylphosphanyl)ethyl)phosphane

: 146816-53-7
{RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl

Guidance literature:: In dichloromethane; a mixt. of P(C2H4P(C6H11)2)3 and RuCl2(PPh3)3 in CH2Cl2 was stirred at room temp. for 0.5 h; performed under Ar using Schlenk technique;; removal of solvent; addn. of Et2O; the ppt. was filtered off, washed with Et2O, and dried under vac.; elem. anal.;;
DOI:10.1021/om00027a046

Reference yield: 85.0%

: 146816-53-7
{RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl

: 146816-58-2
RuHCl(P(C₂H₄P(C₆H₁₁)2)3)

Guidance literature:: With NaOCH₃; In tetrahydrofuran; a mixt. of (RuCl(P(C2H4P(C6H11)2)3))Cl and NaOCH3 in THF was refluxed for 5 h; performed under Ar using Schlenk technique;; removal of solvent; extn. with benzene; removal of benzene; the residue was washed with CH3OH and dried under vac.; recrystn. by slow diffusion of CH3OH into a CH2Cl2 soln.; elem. anal.;;
DOI:10.1021/om00027a046

Reference yield: 78.0%

: 16940-66-2
sodium tetrahydroborate

: 146816-53-7
{RuCl(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*Cl^(1-)={RuCl(P(C₂H₄P(C₆H₁₁)2)3)}Cl

: RuH(BH₄)(P(C₂H₄P(C₆H₁₁)2)3BH₃)

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; a mixt. of (RuCl(P(C2H4P(C6H11)2)3))Cl and NaBH4 in THF was stirred at 20°C overnight; performed under Ar using Schlenk technique;; removal of solvent; extn. with benzene; concn.; addn. of CH3OH; the ppt. was filtered off and dried under vac.; recrystn. by vapor diffusion of CH3OH into a CH2Cl2 soln.; elem. anal.;;
DOI:10.1021/om00027a046