Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)

Base Information

Chemical Name:Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)
CAS No.:176207-28-6
Molecular Formula:C₄₉H₅₀IrP₃
Molecular Weight:924.077
Hs Code.:

Synonyms:Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)

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Chemical Property of Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)

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Technology Process of Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)

There total 4 articles about Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 146728-56-5
[Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)(η(4)-1,5-cyclooctadiene)]Cl

: 176207-28-6
Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)

Guidance literature:: With KO(t)Bu; In dichloromethane; N2 or Ar-atmosphere; stirring for 75 min; evapn., extn. (MePh), filtration, evapn., washing (hexane), drying (vac.); NMR spectroscopy;
DOI:10.1021/om950905z

Reference yield:

: exo-Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)(2-methoxycyclooct-5-en-1-yl)

: 176207-28-6
Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)

Guidance literature:: In benzene; N2 or Ar-atmosphere;
DOI:10.1021/om950905z

Reference yield:

: 146728-56-5
[Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)(η(4)-1,5-cyclooctadiene)]Cl

: 683-60-3
sodium isopropylate

: 176207-28-6
Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)((1,2-η(2))-6-σ-cycloocta-1,4-dienyl)

: exo-Ir(1,1,1-tris((diphenylphosphino)methyl)ethane)(2-isopropoxycyclooct-5-en-1-yl)

Guidance literature:: In dichloromethane; N2 or Ar-atmosphere; stirring for 15 min; evapn., addn. of MePh, evapn., addn. of MePh, filtration, evapn., product mixt. not sepd., total yield 33%; NMR spectroscopy;
DOI:10.1021/om950905z