N,N-bis-(diphenylphosphino)-p-tolylamine

Base Information

• Chemical Name: N,N-bis-(diphenylphosphino)-p-tolylamine
• CAS No.: 80055-00-1
• Molecular Formula: C₃₁H₂₇NP₂
• Molecular Weight: 475.51
• Mol file: 80055-00-1.mol

Synonyms:N,N-bis-(diphenylphosphino)-p-tolylamine

Chemical Property of N,N-bis-(diphenylphosphino)-p-tolylamine

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-bis-(diphenylphosphino)-p-tolylamine

There total 1 articles about N,N-bis-(diphenylphosphino)-p-tolylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

p-toluidine (106-49-0,12221-03-3) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → N,N-bis-(diphenylphosphino)-p-tolylamine (80055-00-1)

Guidance literature:

With triethylamine; In diethyl ether; Ambient temperature;

DOI:10.1016/0584-8539(81)80119-5

Reference yield: 100.0%

C23H28(2)H3CrO3 + N,N-bis-(diphenylphosphino)-p-tolylamine (80055-00-1) → C46H39(2)H3CrNOP2

Guidance literature:

In benzene; for 0.0833333h;

DOI:10.1021/acs.organomet.0c00521

Reference yield: 96.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + N,N-bis-(diphenylphosphino)-p-tolylamine (80055-00-1) → {bis{N,N-bis(diphenylphosphino)-p-tolylamine-P,P'}rhodium(I)} chloride

Guidance literature:

In benzene; (under N2); dissolving of the starting complex and the ligand in benzene, stirring for 24 h at room temp.; filtn., washing of the ppt. (methanol), drying in high vac., elem. anal.;

upstream raw materials:

p-toluidine

chloro-diphenylphosphine

Downstream raw materials:

Fe2(CO)4{μ-Ph2PN(p-tolyl)PPh2}(μ-SCH2CH2CH2S)

diphenyl(methyl)phosphine