[(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

Base Information

• Chemical Name: [(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane
• CAS No.: 80420-28-6
• Molecular Formula: C₅₁H₄₅N₄OP₃PtRh*ClO₄
• Molecular Weight: 1220.3
• Mol file: 80420-28-6.mol

Synonyms:[(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

Chemical Property of [(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

There total 2 articles about [(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

[(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80430-52-0) → [(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80420-28-6)

Guidance literature:

With PPh₃; CO; In dichloromethane; bubbled of CO trough soln. for 10 min, stoich. amt. of phosphorus ligand added, stirred for 15 min, concd. in vac., pptd. with ether; filtered, washed with ether, air dried, elem. anal.;

DOI:10.1016/S0022-328X(00)89059-2

Reference yield:

[1,2-bis(diphenylphosphino)ethane]bis(pyrazolato-N)platinum(II) (63222-34-4) → [(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80420-28-6)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane; acetone

2: PPh₃; CO / dichloromethane

With PPh₃; CO; In dichloromethane; acetone;

DOI:10.1016/S0022-328X(00)89059-2

upstream raw materials:

[(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

[1,2-bis(diphenylphosphino)ethane]bis(pyrazolato-N)platinum(II)