[(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

Base Information

• Chemical Name: [(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane
• CAS No.: 80430-52-0
• Molecular Formula: C₄₀H₄₂N₄P₂PtRh*ClO₄
• Molecular Weight: 1038.18
• Mol file: 80430-52-0.mol

Synonyms:[(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

Chemical Property of [(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

Chemical Property:

Purity/Quality:

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Technology Process of [(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

There total 1 articles about [(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + [1,2-bis(diphenylphosphino)ethane]bis(pyrazolato-N)platinum(II) (63222-34-4) + silver perchlorate → [(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80430-52-0)

Guidance literature:

In dichloromethane; acetone; byproducts: AgCl; suspension of (CODRuCl)2 in acetone and AgClO4 stirred for 30 min, in absence of light under inert atm., filtered to remove AgCl, filtrate added to stoich. amt. of (Pz)2Pt(dpe) in dichloromethane, concd. in vac., ether added to ppn.; filtered, elem. anal.;

DOI:10.1016/S0022-328X(00)89059-2

Reference yield: 86.0%

[(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80430-52-0) → [(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80420-28-6)

Guidance literature:

With PPh₃; CO; In dichloromethane; bubbled of CO trough soln. for 10 min, stoich. amt. of phosphorus ligand added, stirred for 15 min, concd. in vac., pptd. with ether; filtered, washed with ether, air dried, elem. anal.;

DOI:10.1016/S0022-328X(00)89059-2

Reference yield: 80.0%

triphenyl phosphite (101-02-0) + [(COD)Rh(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80430-52-0) → [(CO)(OPh)3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane (80420-30-0)

Guidance literature:

With CO; In dichloromethane; bubbled of CO trough soln. for 10 min, stoich. amt. of phosphorus ligand added, stirred for 15 min, concd. in vac., pptd. with ether; filtered, washed with ether, air dried, elem. anal.;

DOI:10.1016/S0022-328X(00)89059-2

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

[1,2-bis(diphenylphosphino)ethane]bis(pyrazolato-N)platinum(II)

Downstream raw materials:

[(CO)Ph3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

[(CO)2Rh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

[(CO)(OPh)3PRh(μ-Pz)2Pt(dpe)]ClO4 Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane