tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

Base Information

Chemical Name:tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane
CAS No.:197015-50-2
Molecular Formula:C₂₇H₃₆OSSi
Molecular Weight:436.734
Hs Code.:

Synonyms:tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

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Chemical Property of tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

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Technology Process of tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

There total 7 articles about tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 197015-41-1
3-(tert-Butyl-dimethyl-silanyloxy)-2-vinyl-benzaldehyde

: 197015-50-2
tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent / NaH / tetrahydrofuran

2: 1.) m-chloroperbenzoic acid, 2.) HBF₄ / 1.) CH₂Cl₂, 2.) CH₂Cl₂, room temp.

3: 74 percent / CeCl₃ / tetrahydrofuran

4: SOCl₂, pyridine / tetrahydrofuran / 1 h / Ambient temperature

5: NaH / dimethylformamide / 6 h / Ambient temperature

With pyridine; tetrafluoroboric acid; thionyl chloride; cerium(III) chloride; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo971377z

Reference yield:

: 3-((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde

: 197015-50-2
tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

Guidance literature:: Multi-step reaction with 7 steps

1: 98 percent / 4-(dimethylamino)pyridine / pyridine / Ambient temperature

2: 50 percent / LiCl, Pd(PPh₃)4 / tetrahydrofuran / Ambient temperature

3: 84 percent / NaH / tetrahydrofuran

4: 1.) m-chloroperbenzoic acid, 2.) HBF₄ / 1.) CH₂Cl₂, 2.) CH₂Cl₂, room temp.

5: 74 percent / CeCl₃ / tetrahydrofuran

6: SOCl₂, pyridine / tetrahydrofuran / 1 h / Ambient temperature

7: NaH / dimethylformamide / 6 h / Ambient temperature

With pyridine; dmap; tetrafluoroboric acid; tetrakis(triphenylphosphine) palladium⁽⁰⁾; thionyl chloride; cerium(III) chloride; sodium hydride; 3-chloro-benzenecarboperoxoic acid; lithium chloride; In tetrahydrofuran; pyridine; N,N-dimethyl-formamide;
DOI:10.1021/jo971377z

Reference yield:

: 197015-42-2
tert-Butyl-(3-cyclopropylidenemethyl-2-vinyl-phenoxy)-dimethyl-silane

: 197015-50-2
tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) m-chloroperbenzoic acid, 2.) HBF₄ / 1.) CH₂Cl₂, 2.) CH₂Cl₂, room temp.

2: 74 percent / CeCl₃ / tetrahydrofuran

3: SOCl₂, pyridine / tetrahydrofuran / 1 h / Ambient temperature

4: NaH / dimethylformamide / 6 h / Ambient temperature

With pyridine; tetrafluoroboric acid; thionyl chloride; cerium(III) chloride; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo971377z