(3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

Base Information

Chemical Name:(3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane
CAS No.:197015-51-3
Molecular Formula:C₂₇H₃₆O₂SSi
Molecular Weight:452.733
Hs Code.:

Synonyms:(3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

Suppliers and Price of (3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

There total 8 articles about (3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 197015-50-2
tert-Butyl-dimethyl-(3-{2-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-silane

: 197015-51-3
(3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 1.) -78 deg C, 1 h, 2.) -78 C to 0 deg C, 1 h;
DOI:10.1021/jo971377z

Reference yield:

: 197015-41-1
3-(tert-Butyl-dimethyl-silanyloxy)-2-vinyl-benzaldehyde

: 197015-51-3
(3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 84 percent / NaH / tetrahydrofuran

2: 1.) m-chloroperbenzoic acid, 2.) HBF₄ / 1.) CH₂Cl₂, 2.) CH₂Cl₂, room temp.

3: 74 percent / CeCl₃ / tetrahydrofuran

4: SOCl₂, pyridine / tetrahydrofuran / 1 h / Ambient temperature

5: NaH / dimethylformamide / 6 h / Ambient temperature

6: 91 percent / m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 1.) -78 deg C, 1 h, 2.) -78 C to 0 deg C, 1 h

With pyridine; tetrafluoroboric acid; thionyl chloride; cerium(III) chloride; sodium hydride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo971377z

Reference yield:

: 3-((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde

: 197015-51-3
(3-{2-[2-Benzenesulfinyl-1-methyl-eth-(E)-ylidene]-cyclobutyl}-2-vinyl-phenoxy)-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 8 steps

1: 98 percent / 4-(dimethylamino)pyridine / pyridine / Ambient temperature

2: 50 percent / LiCl, Pd(PPh₃)4 / tetrahydrofuran / Ambient temperature

3: 84 percent / NaH / tetrahydrofuran

4: 1.) m-chloroperbenzoic acid, 2.) HBF₄ / 1.) CH₂Cl₂, 2.) CH₂Cl₂, room temp.

5: 74 percent / CeCl₃ / tetrahydrofuran

6: SOCl₂, pyridine / tetrahydrofuran / 1 h / Ambient temperature

7: NaH / dimethylformamide / 6 h / Ambient temperature

8: 91 percent / m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 1.) -78 deg C, 1 h, 2.) -78 C to 0 deg C, 1 h

With pyridine; dmap; tetrafluoroboric acid; tetrakis(triphenylphosphine) palladium⁽⁰⁾; thionyl chloride; cerium(III) chloride; sodium hydride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; lithium chloride; In tetrahydrofuran; pyridine; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo971377z