trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]

Base Information

Chemical Name:trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]
CAS No.:804500-06-9
Molecular Formula:C₅₂H₄₅Cl₂N₂P₃Ru
Molecular Weight:962.84
Hs Code.:

Synonyms:trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]

Chemical Property:

Purity/Quality:

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MSDS Files:: SDS file from LookChem

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Technology Process of trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]

There total 2 articles about trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 150404-18-5
(1-methylimidazol-2-yl)diphenylphosphine

: 804500-06-9
trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]

Guidance literature:: In dichloromethane; byproducts: P(C6H5)3; (Ar), ligand added to suspn. of Ru complex in CH2Cl2 (Ru to ligand ratio1:1), stirred and refluxed for 16 h; evapd., washed (pentane, diethyl ether), dried (vac.), elem. anal.;
DOI:10.1002/ejic.200300892

Reference yield:

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 150404-18-5
(1-methylimidazol-2-yl)diphenylphosphine

: 804500-06-9
trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]

: fac-[chlororuthenium(II) (PPh3) bis[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]] chloride

: mer-[chlororuthenium(II) (PPh3) bis[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]] chloride

Guidance literature:: In dichloromethane; byproducts: P(C6H5)3; (Ar), ligand added to suspn. of Ru complex in CH2Cl2 (Ru to ligand ratio1:2), stirred and refluxed for 16 h; NMR;
DOI:10.1002/ejic.200300892

Reference yield:

: 804500-06-9
trans,mer-[dichlororuthenium(II)(PPh3)2[κ2-P,N-2-(diphenylphosphanyl)-1-methyl-1H-imidazole]]

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

Guidance literature:: In chloroform-d1; further products; standed at room temp. for 3 d; not isolated, detected by NMR;
DOI:10.1002/ejic.200300892