C₅₀H₆₄O₉SeSi

Base Information

Chemical Name:C₅₀H₆₄O₉SeSi
CAS No.:872525-94-5
Molecular Formula:C₅₀H₆₄O₉SeSi
Molecular Weight:916.098
Hs Code.:

C<sub>50</sub>H<sub>64</sub>O<sub>9</sub>SeSi

Synonyms:C₅₀H₆₄O₉SeSi

Suppliers and Price of C₅₀H₆₄O₉SeSi

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₅₀H₆₄O₉SeSi

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₅₀H₆₄O₉SeSi

There total 19 articles about C₅₀H₆₄O₉SeSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 872525-93-4
C₅₀H₇₄O₉Si₂

: 5707-04-0
Phenylselenyl chloride

: 872525-94-5
C₅₀H₆₄O₉SeSi

Guidance literature:: With 2,6-di-tert-butyl-pyridine; In dichloromethane; at 20 ℃; for 9h;
DOI:10.1139/v05-042

Reference yield:

: 872525-98-9
(3aR,7aS)-2,2-Dimethyl-6-oxo-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carbaldehyde

: 872525-94-5
C₅₀H₆₄O₉SeSi

Guidance literature:: Multi-step reaction with 10 steps

1: 77 percent / cesium carbonate / CH₂Cl₂ / 2 h / 20 °C

2: 86 percent / morpholine / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 0.08 h / 20 °C

3: 99 percent / LiAlH[OC(C₂H₅)3]3 / tetrahydrofuran / 1 h / 0 °C

4: 71 percent / diisopropylethylamine / CH₂Cl₂ / 16 h / 20 °C

5: 28 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.5 h / Heating

6: 96 percent / Ne₄NHB(OAc)3; acetic acid / acetonitrile / 19 h / -20 - 0 °C

7: 93 percent / camphorsulfonic acid / acetone / 1 h / 20 °C

8: 86 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.33 h / Heating

9: 100 percent Turnov_. / triethylamine / CH₂Cl₂ / 3 h / 20 °C

10: 71 percent / 2,6-di-tert-butylpyridine / CH₂Cl₂ / 9 h / 20 °C

With morpholine; 2,6-di-tert-butyl-pyridine; lithium tris[(3-ethyl-3-pentyl)oxy]aluminohydride; Ne₄NHB(OAc)3; camphor-10-sulfonic acid; potassium hexamethylsilazane; caesium carbonate; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane; acetone; toluene; acetonitrile; 5: aldol condensation / 8: aldol condensation;
DOI:10.1139/v05-042

Reference yield:

: 872525-77-4
2-(5-formyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide

: 872525-94-5
C₅₀H₆₄O₉SeSi

Guidance literature:: Multi-step reaction with 15 steps

1.1: 3.00 g / tetrahydrofuran; toluene / 1 h / 0 °C

2.1: 92 percent / diisobutylaluminum hydride / tetrahydrofuran; toluene / 1 h / -78 °C

3.1: t-butyllithium / diethyl ether; pentane / 4 h / 0 °C

3.2: 98 percent / diethyl ether; pentane / 0.5 h / 0 °C

4.1: 73 percent / Grubb's second generation catalyst / CH₂Cl₂ / 40 °C

5.1: 80 percent / Dess-Martin periodinane / CH₂Cl₂ / 1 h / 20 °C

6.1: 77 percent / cesium carbonate / CH₂Cl₂ / 2 h / 20 °C

7.1: 86 percent / morpholine / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 0.08 h / 20 °C

8.1: 99 percent / LiAlH[OC(C₂H₅)3]3 / tetrahydrofuran / 1 h / 0 °C

9.1: 71 percent / diisopropylethylamine / CH₂Cl₂ / 16 h / 20 °C

10.1: 28 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.5 h / Heating

11.1: 96 percent / Ne₄NHB(OAc)3; acetic acid / acetonitrile / 19 h / -20 - 0 °C

12.1: 93 percent / camphorsulfonic acid / acetone / 1 h / 20 °C

13.1: 86 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.33 h / Heating

14.1: 100 percent Turnov_. / triethylamine / CH₂Cl₂ / 3 h / 20 °C

15.1: 71 percent / 2,6-di-tert-butylpyridine / CH₂Cl₂ / 9 h / 20 °C

With morpholine; 2,6-di-tert-butyl-pyridine; lithium tris[(3-ethyl-3-pentyl)oxy]aluminohydride; Ne₄NHB(OAc)3; camphor-10-sulfonic acid; tert.-butyl lithium; potassium hexamethylsilazane; diisobutylaluminium hydride; caesium carbonate; Dess-Martin periodane; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; dichloromethane; acetone; toluene; acetonitrile; pentane; 1.1: Wittig reaction / 10.1: aldol condensation / 13.1: aldol condensation;
DOI:10.1139/v05-042