2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3)

Base Information

• Chemical Name: 2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3)
• CAS No.: 20369-54-4
• Molecular Formula: C₃₀H₂₁O₃P
• Molecular Weight: 460.469
• Mol file: 20369-54-4.mol

Synonyms:2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3)

Chemical Property of 2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3)

There total 4 articles about 2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

O2CC(PPh3)2 (7533-53-1) → 2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3) (20369-54-4)

Guidance literature:

Multi-step reaction with 2 steps

1: bis-(2-methoxy-ethyl) ether

2: Ph₃PO / bis-(2-methoxy-ethyl) ether

With Triphenylphosphine oxide; In diethylene glycol dimethyl ether;

DOI:10.1021/ja01016a045

Reference yield:

hexaphenylcarbodiphosphorane (103559-83-7) → 2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3) (20369-54-4)

Guidance literature:

Multi-step reaction with 3 steps

2: bis-(2-methoxy-ethyl) ether

3: Ph₃PO / bis-(2-methoxy-ethyl) ether

With Triphenylphosphine oxide; In diethylene glycol dimethyl ether;

DOI:10.1021/ja01016a045

Reference yield:

Bestmann ylide (73818-55-0,15596-07-3) + terephthalaldehyde, (623-27-8) → 2--4-triphenyl-phosphoranyliden-cyclobutandion-(1,3) (20369-54-4)

Guidance literature:

With Triphenylphosphine oxide; In diethylene glycol dimethyl ether;

DOI:10.1021/ja01016a045

upstream raw materials:

Bestmann ylide

terephthalaldehyde,

O₂CC(PPh₃)2

hexaphenylcarbodiphosphorane