2-Cyclopenten-1-one,4-methyl-4-[(phenylmethoxy)methyl]-,(4S)-(9CI)

Base Information

Chemical Name:2-Cyclopenten-1-one,4-methyl-4-[(phenylmethoxy)methyl]-,(4S)-(9CI)
CAS No.:815587-17-8
Molecular Formula:C14H16 O2
Molecular Weight:0
Hs Code.:
Mol file:815587-17-8.mol

Synonyms:2-Cyclopenten-1-one,4-methyl-4-[(phenylmethoxy)methyl]-,(4S)-(9CI)

Suppliers and Price of 2-Cyclopenten-1-one,4-methyl-4-[(phenylmethoxy)methyl]-,(4S)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of 2-Cyclopenten-1-one,4-methyl-4-[(phenylmethoxy)methyl]-,(4S)-(9CI)

Chemical Property:

PSA：26.30000
LogP:2.73850

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Cyclopenten-1-one,4-methyl-4-[(phenylmethoxy)methyl]-,(4S)-(9CI)

There total 4 articles about 2-Cyclopenten-1-one,4-methyl-4-[(phenylmethoxy)methyl]-,(4S)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 815587-12-3
(4R,5S)-3-((1R,2S)-2-((benzyloxy)methyl)-2-methyl-4-oxocyclopentyl)-4,5-diphenyloxazolidin-2-one

: 815587-17-8
(S)-4-((benzyloxy)methyl)-4-methylcyclopent-2-enone

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃;
DOI:10.1021/jo040215h

Reference yield: 25.0%

: 815587-23-6
(1R,4S)-4-((benzyloxy)methyl)-4-methylcyclopent-2-enyl ethyl carbonate

: 108-59-8
malonic acid dimethyl ester

: 815587-17-8
(S)-4-((benzyloxy)methyl)-4-methylcyclopent-2-enone

: dimethyl 2-((1S,4S)-4-((benzyloxy)methyl)-4-methylcyclopent-2-enyl)malonate

: dimethyl 2-((1R,4S)-4-((benzyloxy)methyl)-4-methylcyclopent-2-enyl)malonate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1021/jo040215h

Reference yield:

: 815587-19-0
(1R,4S)-4-((benzyloxy)methyl)-4-methylcyclopent-2-enol

: 815587-17-8
(S)-4-((benzyloxy)methyl)-4-methylcyclopent-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / pyridine / CH₂Cl₂ / 0.25 h / 20 °C

2: 25 percent / Pd(PPh₃)4; NaH / dimethylformamide

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo040215h