6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate

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Chemical Name:6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate
CAS No.:460731-79-7
Molecular Formula:C₂₃H₂₃NO₉
Molecular Weight:457.437
Hs Code.:

Synonyms:6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate

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Chemical Property of 6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate

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Technology Process of 6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate

There total 8 articles about 6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 228242-69-1
7-aminocarbomethoxy-2,2-dimethyl-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-(3aR,4S,7R,7aS)-4,7-dihydro[d][1,3]dioxol-4-yl benzoate

: 460731-79-7
6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate

Guidance literature:: With Dowex 50x8-100; In methanol; Ambient temperature;
DOI:10.1016/S0040-4039(99)00433-5

Reference yield:

: 108-36-1
1,3-dibromobenzene

: 460731-79-7
6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate

Guidance literature:: Multi-step reaction with 7 steps

1.1: Escherichia coli JM₁₀₉ (pDTG₆₀₁A)

2.1: p-toluenesulfonic acid

3.1: 1.3 g / NaIO₄ / methanol; various solvent(s) / 16 h / 20 °C

4.1: Pd(PPh₃)4; aq. Na₂CO₃ / benzene; ethanol / 8 h / Heating

4.2: 31 percent / Mo(CO)6 / benzene; ethanol / 12 h

5.1: cerium chloride / methanol / 0.08 h

5.2: 50 percent / NaBH₄ / methanol / 0.5 h / 0 °C

6.1: 52 percent / tributylphosphine; DEAD / tetrahydrofuran / 2 h / 25 °C

7.1: Dowex 50 x 8-100 ion-exchange resin / methanol / 12 h / 20 °C

With sodium periodate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; cerium(III) chloride; tributylphosphine; Dowex 50 x 8-100 ion-exchange resin; Escherichia coli JM₁₀₉ (pDTG₆₀₁A); sodium carbonate; toluene-4-sulfonic acid; diethylazodicarboxylate; In tetrahydrofuran; methanol; ethanol; benzene;
DOI:10.1021/jo020129m

Reference yield:

: 228242-61-3
3,5-dibromo-(1S,2S)-3,5-cyclohexadiene-1,2-diol

: 460731-79-7
6-aminocarbomethoxy-1,2-dihydroxy-5-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-cyclohexene-1-yl benzoate

Guidance literature:: Multi-step reaction with 6 steps

1.1: p-toluenesulfonic acid

2.1: 1.3 g / NaIO₄ / methanol; various solvent(s) / 16 h / 20 °C

3.1: Pd(PPh₃)4; aq. Na₂CO₃ / benzene; ethanol / 8 h / Heating

3.2: 31 percent / Mo(CO)6 / benzene; ethanol / 12 h

4.1: cerium chloride / methanol / 0.08 h

4.2: 50 percent / NaBH₄ / methanol / 0.5 h / 0 °C

5.1: 52 percent / tributylphosphine; DEAD / tetrahydrofuran / 2 h / 25 °C

6.1: Dowex 50 x 8-100 ion-exchange resin / methanol / 12 h / 20 °C

With sodium periodate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; cerium(III) chloride; tributylphosphine; Dowex 50 x 8-100 ion-exchange resin; sodium carbonate; toluene-4-sulfonic acid; diethylazodicarboxylate; In tetrahydrofuran; methanol; ethanol; benzene;
DOI:10.1021/jo020129m