Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate

Base Information

Chemical Name:Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate
CAS No.:86832-63-5
Molecular Formula:C₂₃H₂₀Cl₂N₂O₃S
Molecular Weight:475.395
Hs Code.:

Synonyms:Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate

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Chemical Property of Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate

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Technology Process of Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate

There total 5 articles about Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 86832-62-4
(S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

: 86832-63-5
Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate

Guidance literature:: With triethylamine; In dichloromethane; at 5 - 15 ℃; for 2h;
DOI:10.1021/jo00168a036

Reference yield: 76.0%

: 86833-34-3
4-Chloro-3-chloromethyl-2-[(1R,5R)-3-(dichloro-phenyl-methyl)-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl]-but-2-enoic acid benzyl ester

: 86832-63-5
Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate

Guidance literature:: With zinc; In dichloromethane; acetic acid; at 5 ℃; for 0.5h;
DOI:10.1021/jo00168a036

Reference yield:

: 86832-59-9
(R)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3-methyl-but-3-enoic acid benzyl ester

: 86832-63-5
Benzyl 2-(3-Benzyl-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl)-4-chloro-3-(chloromethyl)-2-butenoate

Guidance literature:: Multi-step reaction with 3 steps

1: 50 percent / NaCl, conc. H₂SO₄ / CHCl₃; H₂O / Ambient temperature; 1) electrolysis, Pt electrodes, undivided cell, 10 mA/cm², 15 F/mol, 2) electrolysis 5 F/mol, irradiation

2: 96 percent / Zn powder, AcOH / CH₂Cl₂ / 0.5 h / 0 °C

3: 86 percent / Et₃N / CH₂Cl₂ / 2 h / 5 - 15 °C

With sulfuric acid; acetic acid; triethylamine; sodium chloride; zinc; In dichloromethane; chloroform; water;
DOI:10.1021/jo00168a036