8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

Base Information

Chemical Name:8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine
CAS No.:334874-35-0
Molecular Formula:C₁₆H₁₇N₃
Molecular Weight:251.331
Hs Code.:

Synonyms:8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

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Technology Process of 8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

There total 1 articles about 8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 334874-40-7
N-(2-amino-5-methylbenzoyl)-8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

: 334874-35-0
8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

: 334874-39-4
N-(2-amino-5-methylbenzyl)-8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

Guidance literature:: With borane-THF; In tetrahydrofuran; for 1h; Heating;
DOI:10.1021/jo0010882

Reference yield: 65.0%

: 4693-02-1
6-nitroisatoic anhydride

: 334874-35-0
8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

: 334874-36-1
N-(2-amino-5-nitrobenzoyl)-8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

Guidance literature:: In tetrahydrofuran; for 3h; Heating;
DOI:10.1021/jo0010882

Reference yield:

: 334874-35-0
8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

: 334874-39-4
N-(2-amino-5-methylbenzyl)-8-amino-2-methyl-5,11-methano-5,6,11,12-tetrahydrodibenzo[b,f][1,5]diazocine

Guidance literature:: Multi-step reaction with 3 steps

1: 66 percent / dicyclohexylcarbodiimide / dimethylformamide / 5 h / 20 °C

2: 98 percent / H₂ / Pd/C / ethanol; CHCl₃ / 3 h / 20 °C / 1520.1 Torr

3: 56 percent / BH₃-THF / tetrahydrofuran / 1 h / Heating

With borane-THF; hydrogen; dicyclohexyl-carbodiimide; palladium on activated charcoal; In tetrahydrofuran; ethanol; chloroform; N,N-dimethyl-formamide;
DOI:10.1021/jo0010882