Technology Process of C36H48O6Si
There total 1 articles about C36H48O6Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
ethyl 2,2-dimethyl-3-oxobutanoate;
With
triethylamine; B-chlorodiisopinocampheylborane;
In
diethyl ether;
at 0 ℃;
(S)-5-(benzyloxy)-3-(tert-butyldiphenylsiloxy)pentanal;
In
diethyl ether;
at -98 ℃;
With
dihydrogen peroxide;
In
methanol; diethyl ether;
pH=7;
optical yield given as %de;
aq. buffer;
DOI:10.1073/pnas.1015270108
- Guidance literature:
-
With
acetic acid; tetramethylammonium triacetoxyborohydride;
In
acetonitrile;
at -15 ℃;
DOI:10.1073/pnas.1015270108
- Guidance literature:
-
Multi-step reaction with 5 steps
1: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / -15 °C
2: (+/-)-CSA / toluene / Reflux
3: 2,6-dimethylpyridine / dichloromethane
4: lithium diisopropyl amide / tetrahydrofuran / -78 °C
5: dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen / ethanol / 35 - 40 °C / 58505.9 Torr
With
2,6-dimethylpyridine; dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen; acetic acid; tetramethylammonium triacetoxyborohydride; lithium diisopropyl amide;
In
tetrahydrofuran; ethanol; dichloromethane; toluene; acetonitrile;
DOI:10.1073/pnas.1015270108
