[4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

Base Information

Chemical Name:[4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane
CAS No.:332866-04-3
Molecular Formula:C₁₇H₂₈O₂Si
Molecular Weight:293.483
Hs Code.:

[4-<sup>13</sup>C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

Synonyms:[4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

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Technology Process of [4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

There total 5 articles about [4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 100-39-0
benzyl bromide

: 332865-91-5
[1-¹³C]-(E)-4-((tert-butyldimethylsilyl)oxy)but-2-en-1-ol

: 332866-04-3
[4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

Guidance literature:: [1-¹³C]-(E)-4-((tert-butyldimethylsilyl)oxy)but-2-en-1-ol; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; Inert atmosphere;

benzyl bromide; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1039/c4cc00177j

Reference yield:

: 90838-72-5,110410-38-3,134435-95-3,86633-16-1,81925-28-2,86646-19-7
(E)-tert-butyldimethyl[3-(tributylstannyl)prop-2-enyloxy]silane

: 332866-04-3
[4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: nBuLi / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 69 percent / tetrahydrofuran; hexane / 2 h / -78 °C

2.1: 90 percent / DIBAL / CH₂Cl₂; hexane / 0.58 h / -78 °C

3.1: NaH / 1,2-dimethoxy-ethane / 0.17 h / 0 °C

3.2: 1,2-dimethoxy-ethane / 3 h / 20 °C

With n-butyllithium; sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; dichloromethane;
DOI:10.1016/S0040-4020(00)01148-0

Reference yield:

: 332875-19-1
C₉⁽¹³⁾CH₂₀O₂Si

: 332866-04-3
[4-¹³C]-(E)-((4-(benzyloxy)but-2-en-1-yl)oxy)(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 90 percent / DIBAL / CH₂Cl₂; hexane / 0.58 h / -78 °C

2.1: NaH / 1,2-dimethoxy-ethane / 0.17 h / 0 °C

2.2: 1,2-dimethoxy-ethane / 3 h / 20 °C

With sodium hydride; diisobutylaluminium hydride; In 1,2-dimethoxyethane; hexane; dichloromethane;
DOI:10.1016/S0040-4020(00)01148-0