phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside

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Chemical Name:phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside
CAS No.:288585-02-4
Molecular Formula:C₄₈H₆₈O₅SeSi₃
Molecular Weight:888.281
Hs Code.:

Synonyms:phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside

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Chemical Property of phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside

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Technology Process of phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside

There total 4 articles about phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 4028-23-3
Allylchlorodimethylsilane

: 288584-99-6
phenyl 3,4-bis-O-tert-butyldimethylsilyl-6-O-trityl-1-seleno-β-D-glucose

: 288585-02-4
phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside

Guidance literature:: With pyridine; 3 A molecular sieve; at 20 ℃; for 1h;
DOI:10.1016/j.tet.2005.02.025

Reference yield:

: 122350-80-5
1,5-anhydro-2-deoxy-6-O-trityl-D-arabino-hex-1-enitol

: 288585-02-4
phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: 85 percent / imidazole / dimethylformamide

2.1: dimethyldioxirane / CH₂Cl₂

2.2: 66 percent / Et₃N / CH₂Cl₂

3.1: 67 percent / DMAP; Et₃N / toluene

With 1H-imidazole; dmap; 3,3-dimethyldioxirane; triethylamine; In dichloromethane; N,N-dimethyl-formamide; toluene; 1.1: silylation / 2.1: Addition / 2.2: Ring cleavage / 3.1: Condensation;
DOI:10.1016/S0040-4039(00)00556-6

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 288585-02-4
phenyl 2-O-(allyl(dimethyl)silyl)-3,4-bis-O-(tert-butyl(dimethyl)silyl)-6-O-(triphenylmethyl)-1-seleno-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: 85 percent / imidazole / dimethylformamide

2.1: dimethyldioxirane / CH₂Cl₂

2.2: 66 percent / Et₃N / CH₂Cl₂

3.1: 67 percent / DMAP; Et₃N / toluene

With 1H-imidazole; dmap; 3,3-dimethyldioxirane; triethylamine; In dichloromethane; N,N-dimethyl-formamide; toluene; 1.1: silylation / 2.1: Addition / 2.2: Ring cleavage / 3.1: Condensation;
DOI:10.1016/S0040-4039(00)00556-6