(2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane

Base Information

Chemical Name:(2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane
CAS No.:552833-16-6
Molecular Formula:C₃₈H₆₇IO₃S₂Si₃
Molecular Weight:847.241
Hs Code.:

Synonyms:(2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane

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Technology Process of (2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane

There total 2 articles about (2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 994-30-9
triethylsilyl chloride

: 358395-59-2
(2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-1,1-diethylthio-5-iodohexane-2,4-diol

: 552833-16-6
(2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane

Guidance literature:: In pyridine; at 20 ℃;
DOI:10.1016/S0040-4020(03)00258-8

Reference yield:

: tert-Butyl-[(R)-2-((3aS,5R,6aS)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-iodo-ethoxy]-diphenyl-silane

: 552833-16-6
(2S,4R,5R)-6-(tert-butyldiphenylsilyloxy)-2,4-di(triethylsilyloxy)-1,1-diethylthio-5-iodohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / ZnCl₂ / 0.5 h / -20 °C

2: 73 percent / pyridine / 20 °C

With zinc(II) chloride; In pyridine;
DOI:10.1016/S0040-4020(03)00258-8