(Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal

Base Information

Chemical Name:(Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal
CAS No.:111670-41-8
Molecular Formula:C₂₆H₃₃F₃O₂Si
Molecular Weight:462.628
Hs Code.:

Synonyms:(Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal

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Chemical Property of (Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal

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Technology Process of (Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal

There total 5 articles about (Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 111670-40-7
(Z)-(2S,3R)-3-(tert-Butyl-diphenyl-silanyloxy)-11,11,11-trifluoro-undec-5-ene-1,2-diol

: 111670-41-8
(Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal

Guidance literature:: With lead(IV) acetate; potassium carbonate; In dichloromethane; at -78 ℃;
DOI:10.1139/v87-244

Reference yield:

: 4224-70-8
6-bromohexanoic acid

: 111670-41-8
(Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal

Guidance literature:: Multi-step reaction with 5 steps

1: sulfur tetrafluoride / 130 °C

2: acetonitrile / Heating

3: BuLi / tetrahydrofuran / -78 deg C to room temp.

4: 91 percent / TFA / tetrahydrofuran; H₂O / 60 °C

5: 87 percent / Pb(OAc)4, K₂CO₃ / CH₂Cl₂ / -78 °C

With lead(IV) acetate; n-butyllithium; sulfur tetrafluoride; potassium carbonate; trifluoroacetic acid; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1139/v87-244

Reference yield:

: 111670-37-2
6-Bromo-1,1,1-trifluorohexane

: 111670-41-8
(Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10,10,10-trifluoro-dec-4-enal

Guidance literature:: Multi-step reaction with 4 steps

1: acetonitrile / Heating

2: BuLi / tetrahydrofuran / -78 deg C to room temp.

3: 91 percent / TFA / tetrahydrofuran; H₂O / 60 °C

4: 87 percent / Pb(OAc)4, K₂CO₃ / CH₂Cl₂ / -78 °C

With lead(IV) acetate; n-butyllithium; potassium carbonate; trifluoroacetic acid; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1139/v87-244