Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Base Information

Chemical Name:Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine
CAS No.:203192-36-3
Molecular Formula:C₂₄H₃₂ClNNiP₃*F₆P
Molecular Weight:666.553
Hs Code.:

Ni(II)Cl(P(CH<sub>3</sub>)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Synonyms:Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Chemical Property:

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Technology Process of Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

There total 2 articles about Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.5%

: 17084-13-8
potassium hexafluorophosphate

: 103421-62-1,19232-05-4,20087-67-6
trans-[dichlorobis(trimethylphosphane)nickel(II)]

: 65423-44-1
(2-diphenylphosphino)benzeneamine

: 85096-37-3
C₃₆H₃₀N₂NiP₂

: cis-Ni(II)(o-diphenylphosphino)aniline (PF₆)2

: 203192-36-3
Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Guidance literature:: In dichloromethane; byproducts: H2, KCl; N-compd. (solid) addn. to mixture of Ni-compd. and KPF6 soln., stirring(3 h, room temp., under N2), pptn. filtered off, filtrate concn., Et2O addn., solid after vigorous stirring; solid filtration off, washing (water, Et2O, MeOH), recrystn. (CH2Cl2/MeOH/C6H6 3/1/3), vac. drying;
DOI:10.1021/ja9738440

Reference yield: 9.0%

: 17084-13-8
potassium hexafluorophosphate

: Ni(II)Cl₂P(CH₃)3 (o-diphenylphosphino)aniline

: 203192-36-3
Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Guidance literature:: In dichloromethane; KPF6 addn., stirring (room temp., 3 h); inorg. salts filtration off, filtrate concn., Et2O addn., solid after stirring; dissoln. (EtOH), standing (3 d), crystn.;
DOI:10.1021/ja9738440