1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol

Base Information

Chemical Name:1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol
CAS No.:627885-95-4
Molecular Formula:C₄₆H₅₄O₁₁Si₂
Molecular Weight:839.099
Hs Code.:

Synonyms:1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol

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Chemical Property of 1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol

Chemical Property:

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Technology Process of 1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol

There total 1 articles about 1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 38876-99-2
1L-chiro-inositol

: 69304-37-6
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane

: 98-88-4
benzoyl chloride

: 627885-95-4
1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol

: C₄₆H₅₄O₁₁Si₂

: C₄₄H₇₂O₁₀Si₄

Guidance literature:: 1L-chiro-inositol; 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane; With 1H-imidazole; dmap; In N,N-dimethyl-formamide; at 20 ℃;

benzoyl chloride; With pyridine; dmap; Further stages.;
DOI:10.1002/ejoc.200300252

Reference yield: 90.0%

: 627885-95-4
1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol

: 627886-01-5
1,4,5,6-tetra-O-benzoyl-L-chiro-inositol

Guidance literature:: With (HF)n*pyridine; In tetrahydrofuran;
DOI:10.1002/ejoc.200300252

Reference yield:

: 627885-95-4
1,4,5,6-tetra-O-benzoyl-2,3-O-(tetraisopropyldisiloxane-1',3'-diyl)-L-chiro-inositol

: 2-amino-2-deoxy-D-glucopyranosyl-α(1->3)-L-chiro-inositol

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / (HF)n*pyridine / tetrahydrofuran

2: 58 percent / TMSOTf / diethyl ether

3: 100 percent / NaOMe / methanol / 20 °C

4: 95 percent / hydrogen / Pd/C / ethanol; H₂O

With trimethylsilyl trifluoromethanesulfonate; (HF)n*pyridine; hydrogen; sodium methylate; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; ethanol; water;
DOI:10.1002/ejoc.200300252