O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate

Base Information

• Chemical Name: O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate
• CAS No.: 433935-37-6
• Molecular Formula: C₁₂H₁₆O₄S₂
• Molecular Weight: 288.389
• Mol file: 433935-37-6.mol

Synonyms:O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate

Chemical Property of O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate

There total 1 articles about O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

potassium ethyl xanthogenate (140-89-6) + 3,4,5-Trimethoxyaniline (24313-88-0) → O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate (433935-37-6)

Guidance literature:

3,4,5-Trimethoxyaniline; With hydrogenchloride; sodium nitrite; In water; at 0 ℃; for 0.5h; Inert atmosphere;

potassium ethyl xanthogenate; In water; at 65 ℃; for 0.5h;

DOI:10.1002/anie.201605597

Reference yield: 95.0%

O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate (433935-37-6) → 3,4,5-trimethoxyphenylmercaptan (16807-30-0) + 1,1'-(3,4,5-trimethoxyphenyl)disulfide (16807-29-7)

Guidance literature:

With sodium hydroxide; In ethanol; water; at 65 ℃; for 1.5h;

DOI:10.1016/j.bmcl.2013.06.009

Reference yield: 94.0%

O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate (433935-37-6) → 3,4,5-trimethoxyphenylmercaptan (16807-30-0)

Guidance literature:

O-ethyl-S-(3,4,5-trimethoxyphenyl)carbonodithioate; With sodium hydroxide; In ethanol; at 65 ℃; for 3h;

With hydrogenchloride; In ethanol; water; pH=5;

DOI:10.1016/j.ejmech.2018.08.074

upstream raw materials:

potassium ethyl xanthogenate

3,4,5-Trimethoxyaniline

Downstream raw materials:

3,4,5-trimethoxyphenylmercaptan

Refernces

• 1、 Li, Weihe,Wang, Hao,Liu, Shengping,Feng, Hua,Benassi, Enrico,Qian, Bo. "Iodine/Manganese Catalyzed Sulfenylation of Indole via Dehydrogenative Oxidative Coupling in Anisole". supporting information. p. 2666 - 2671. Retrieved 2020/05/25.
• 2、 Zhou, Bin,Faridoon,Tian, Xiaobo,Li, Jian,Guan, Dongliang,Zheng, Xing,Guo, Yu,Huang, Wei. "On-resin peptide ligation via C-terminus benzyl ester". supporting information. p. 1123 - 1126. Retrieved 2018/04/10.