dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium

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Chemical Name:dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium
CAS No.:475995-44-9
Molecular Formula:C₂₃H₂₇Cl₂NSiTi
Molecular Weight:464.346
Hs Code.:

Synonyms:dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium

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Chemical Property of dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium

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Technology Process of dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium

There total 1 articles about dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: tetrakis(dimethylamido)titanium(IV)

: 475995-50-7
N-(tert-butyl)(3,4-diphenyl-2,4-cyclopentadien-1-yl)dimethylsilanamine

: 75-78-5,30107-43-8
dimethylsilicon dichloride

: 475995-44-9
dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium

Guidance literature:: In octane; under inert atm.; ligand, Ti(NMe2)4 dissolved in octane; soln. refluxed overnight; solvent removed (vac.); oil dissolved in toluene; Me2SiCl2 added; mixt. stirred for 2 ds; solvent removed (vac.); hexane added; mixt. stirred for 3 h; solid collected on frit; washed (cold hexane); dried (vac.); dissolved (toluene, hexane); after 2 min soln. filtered and put aside at room temp.; put into freezer overnight (-27°C)...;
DOI:10.1021/ja070061y

Reference yield: 74.5%

: 475995-44-9
dichloro[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium

: 917-54-4
methyllithium

: 475995-45-0
dimethyl[N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-η)-3,4-diphenyl-2,4-cyclopentadien-1-yl]silanaminato-(2-)-κ-N]titanium

Guidance literature:: In diethyl ether; toluene; under inert atm.; Ti complex dissolved in toluene; soln. of MeLi in ether added dropwise with stirring over 1 min; soln. stirred for 45 min; volatiles removed (vac.); residue extd. (hot hexane); soln. filtered hot; put into freezer overnight; solvent decanted; crystals washed (cold hexane); dried (vac.); elem. anal.;
DOI:10.1021/ja070061y