1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane

Base Information

• Chemical Name: 1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane
• CAS No.: 136292-94-9
• Molecular Formula: C₂₄H₄₀N₄Si₅
• Molecular Weight: 525.036
• Mol file: 136292-94-9.mol

Synonyms:1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane

Chemical Property of 1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane

There total 1 articles about 1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane (812-36-2) + (Phenyldimethylsilyl)diazomethane → 1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane (136292-94-9)

Guidance literature:

With lithium diisopropyl amide; Yield given. Multistep reaction; 1.) Et₂O, -40 deg C, 2.) Et₂O, -55 deg C;

DOI:10.1016/0022-328X(95)00324-J

Reference yield: 67.0%

1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane (136292-94-9) → 1,5-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,4,4-hexamethyl-6,7,8-trithia-2,3,4-trisila-bicyclo[3.2.1]octane

Guidance literature:

With sulfur; In decalin; at 120 ℃;

Reference yield: 14.0%

1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane (136292-94-9) → 4,5-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,6,6-hexamethyl-3,6-dihydro-2H-[1,2,3,6]selenatrisiline + 1,5-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,4,4-hexamethyl-6,7,8-triselena-2,3,4-trisila-bicyclo[3.2.1]octane

Guidance literature:

With selenium; In decalin; at 165 - 170 ℃; for 0.75h;

upstream raw materials:

1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane

Downstream raw materials:

1,3-Bis-(dimethyl-phenyl-silanyl)-2,2,4,4,5,5-hexamethyl-2,4,5-trisila-bicyclo[1.1.1]pentane

1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane

(3R,4S)-3-(tert-Butoxy-dimethyl-silanyl)-3,4-bis-(dimethyl-phenyl-silanyl)-1,1,2,2-tetramethyl-[1,2]disiletane

(3R,4R)-3-(tert-Butoxy-dimethyl-silanyl)-3,4-bis-(dimethyl-phenyl-silanyl)-1,1,2,2-tetramethyl-[1,2]disiletane