1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane

Base Information

• Chemical Name: 1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane
• CAS No.: 136262-80-1
• Molecular Formula: C₂₄H₄₀Si₅
• Molecular Weight: 469.009
• Mol file: 136262-80-1.mol

Synonyms:1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane

Chemical Property of 1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane

There total 1 articles about 1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.6%

1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane (136292-94-9) → 1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane (136262-80-1)

Guidance literature:

In various solvent(s); at -55 ℃; Irradiation;

DOI:10.1021/ja00020a067

Reference yield:

1,4-Bis-(dimethyl-phenyl-silanyl)-2,2,3,3,5,5-hexamethyl-2,3,5-trisila-bicyclo[2.1.0]pentane (136262-80-1) + tert-butyl alcohol (75-65-0) → (3R,4S)-3-(tert-Butoxy-dimethyl-silanyl)-3,4-bis-(dimethyl-phenyl-silanyl)-1,1,2,2-tetramethyl-[1,2]disiletane (136292-95-0,136292-96-1) + (3R,4R)-3-(tert-Butoxy-dimethyl-silanyl)-3,4-bis-(dimethyl-phenyl-silanyl)-1,1,2,2-tetramethyl-[1,2]disiletane (136292-95-0,136292-96-1)

Guidance literature:

In various solvent(s); Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/ja00020a067

upstream raw materials:

1,3-bis(dimethylphenylsilyldiazomethyl)-1,1,2,2,3,3-hexamethyltrisilane

Downstream raw materials:

(3R,4S)-3-(tert-Butoxy-dimethyl-silanyl)-3,4-bis-(dimethyl-phenyl-silanyl)-1,1,2,2-tetramethyl-[1,2]disiletane

(3R,4R)-3-(tert-Butoxy-dimethyl-silanyl)-3,4-bis-(dimethyl-phenyl-silanyl)-1,1,2,2-tetramethyl-[1,2]disiletane