dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate

Base Information

• Chemical Name: dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate
• CAS No.: 1312703-30-2
• Molecular Formula: C₂₂H₁₉NO₄
• Molecular Weight: 361.397
• Mol file: 1312703-30-2.mol

Synonyms:dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate

Chemical Property of dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate

There total 1 articles about dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2,5-dibromoaniline (3638-73-1) + 4-methoxycarbonylphenylboronic acid (99768-12-4) → dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate (1312703-30-2)

Guidance literature:

With palladium diacetate; sodium carbonate; In water; N,N-dimethyl-formamide; at 60 ℃;

DOI:10.1021/ja403810k

Reference yield: 98.0%

dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate (1312703-30-2) → 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylic acid (1312703-28-8)

Guidance literature:

dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate; With potassium hydroxide; In ethanol; water; at 60 ℃; Reflux;

With hydrogenchloride; In water; pH=Ca. 2;

DOI:10.1021/ja403810k

Reference yield: 66.3%

1-methyl-4-nitrosobenzene (623-11-0) + dimethyl 2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylate (1312703-30-2) → C29H24N2O4

Guidance literature:

With acetic acid; at 90 ℃; for 24h;

DOI:10.1021/acs.inorgchem.1c00217

upstream raw materials:

2,5-dibromoaniline

4-methoxycarbonylphenylboronic acid

Downstream raw materials:

2’-amino-1,1’:4,1’’-terphenyl-4,4’’-dicarboxylic acid