(2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine

Base Information

• Chemical Name: (2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine
• CAS No.: 82495-82-7
• Molecular Formula: C₂₆H₃₇NOSi
• Molecular Weight: 407.671
• Mol file: 82495-82-7.mol

Synonyms:(2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine

Chemical Property of (2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine

There total 1 articles about (2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-Benzyl-N-[(2Z,4E)-(S)-1-benzyl-3,4-dimethyl-5-(2-trimethylsilanyl-ethoxy)-penta-2,4-dienyl]-4-methyl-benzenesulfonamide (82495-78-1,82495-79-2,82535-50-0,82535-51-1) → (2S)-(Z,Z)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine (82495-83-8) + (2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine (82495-82-7)

Guidance literature:

With disodium hydrogenphosphate; sodium amalgam; Heating;

DOI:10.1021/ja00385a029

Reference yield: 94.0%

(2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine (82495-82-7) + 4-((3aR,4R,5S,7S,7aS)-5-Allyl-5-benzenesulfonyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-4-yl)-3-oxo-butyric acid methyl ester → 4-((3aR,4R,5S,7S,7aS)-5-Allyl-5-benzenesulfonyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-4-yl)-N-benzyl-N-[(2Z,4E)-(S)-1-benzyl-3,4-dimethyl-5-(2-trimethylsilanyl-ethoxy)-penta-2,4-dienyl]-3-oxo-butyramide (109611-58-7)

Guidance literature:

With sodium hydrogencarbonate; In toluene; for 36h; Heating;

Reference yield: 94.0%

(2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine (82495-82-7) + 3-Oxo-4-[(3aR,4S,7S,7aS)-2,2,3a,7-tetramethyl-5-prop-2-en-(E)-ylidene-hexahydro-benzo[1,3]dioxol-4-yl]-butyric acid methyl ester (109611-57-6) → N-Benzyl-N-[(2Z,4E)-(S)-1-benzyl-3,4-dimethyl-5-(2-trimethylsilanyl-ethoxy)-penta-2,4-dienyl]-3-oxo-4-[(3aR,4S,7S,7aS)-2,2,3a,7-tetramethyl-5-prop-2-en-(E)-ylidene-hexahydro-benzo[1,3]dioxol-4-yl]-butyramide (109611-59-8)

Guidance literature:

With sodium hydrogencarbonate; In toluene; for 36h; Heating;

upstream raw materials:

N-Benzyl-N-[(2Z,4E)-(S)-1-benzyl-3,4-dimethyl-5-(2-trimethylsilanyl-ethoxy)-penta-2,4-dienyl]-4-methyl-benzenesulfonamide

Downstream raw materials:

(2S)-N-benzyl-<(Z,E)-2-(6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl)hexa-3,5-dienyl>-3-oxobutanamide

(2'S)-3,3-dimethyl-6-oxocyclohex-1-enyl-1-((Z,E)-N,N-benzyl-2'-<6'-(trimethylsilyl)ethoxy-4',5'-dimethyl-1'-phenyl>hexa-3',5'-dienyl)carboxamide

(1S,2R,1'R,5R,7R,8S,9R,10R)-N-benzyl-N-<1'-benzyl-3',4'-dimethyl-5-<2-(trimethylsilyl)ethoxy>penta-2',4'(Z,E)-dienyl>-2-(benzoyloxy)-8,9-dihydroxy-8,10-dimethyl-5-oxobicyclo<5.4.0>undec-3-ene-4-carboxamide 8,9-acetonide

(1S,2R,1'R,5R,7R,8S,9R,10R)-N-benzyl-N-<1'-benzyl-3',4'-dimethyl-5-<2-(trimethylsilyl)ethoxy>penta-2',4'(Z,E)-dienyl>-5-(benzoyloxy)-8,9-dihydroxy-8,10-dimethyl-12-oxatricyclo<5.4.0.1^2,5>dodeca-3-ene-4-carboxamide 8,9-acetonide