4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Base Information

Chemical Name:4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside
CAS No.:129728-65-0
Molecular Formula:C₂₈H₃₄FNO₁₇
Molecular Weight:675.573
Hs Code.:

Synonyms:4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

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Chemical Property of 4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

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Technology Process of 4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

There total 9 articles about 4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.5%

: 129728-62-7
4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-α-D-mannopyranoside

: 13242-53-0
acetobromomannose

: 129728-65-0
4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

: 129728-66-1
4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-2-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

: 4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-2,3-di-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Guidance literature:: With mercury(II) cyanide; mercury dibromide; In acetonitrile; for 5h; Ambient temperature;
DOI:10.1016/0008-6215(90)84297-8

Reference yield:

: 100-02-7,78813-13-5,89830-32-0
4-nitro-phenol

: 129728-65-0
4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 60 percent / SnCL₄ / CH₂Cl₂ / 4 h / Heating

2: 92 percent / Amberlyst A-26 (OH-) / methanol / Ambient temperature

3: 83 percent / 4-toluenesulfonic acid monohydrate / acetone / Ambient temperature

4: 98 percent / pyridine / Ambient temperature

5: 94 percent / trifluoroacetic acid, water / CHCl₃ / 2 h / Ambient temperature

6: 1) Hg(CN)2, HgBr₂ / benzene, nitromethane, 1) 4A molecular sieves, boiling, 2) 41h, 45-48 deg C

With pyridine; Amberlyst A-26 (OH-); p-toluenesulfonic acid monohydrate; water; mercury(II) cyanide; tin(IV) chloride; trifluoroacetic acid; mercury dibromide; In methanol; dichloromethane; chloroform; acetone;
DOI:10.1016/0008-6215(90)84297-8

Reference yield:

: 129728-70-7
4-nitrophenyl 6-deoxy-6-fluoro-α-D-mannopyranoside

: 129728-65-0
4-nitrophenyl 4-O-acetyl-6-deoxy-6-fluoro-3-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 83 percent / 4-toluenesulfonic acid monohydrate / acetone / Ambient temperature

2: 98 percent / pyridine / Ambient temperature

3: 94 percent / trifluoroacetic acid, water / CHCl₃ / 2 h / Ambient temperature

4: 1) Hg(CN)2, HgBr₂ / benzene, nitromethane, 1) 4A molecular sieves, boiling, 2) 41h, 45-48 deg C

With pyridine; p-toluenesulfonic acid monohydrate; water; mercury(II) cyanide; trifluoroacetic acid; mercury dibromide; In chloroform; acetone;
DOI:10.1016/0008-6215(90)84297-8