(S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine

Base Information

Chemical Name:(S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine
CAS No.:177036-08-7
Molecular Formula:C₂₆H₃₅NO₃
Molecular Weight:409.569
Hs Code.:

Synonyms:(S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine

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Chemical Property of (S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine

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Technology Process of (S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine

There total 6 articles about (S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 158818-68-9
(S)-2-(2-tert-Butoxycarbonylamino-5-methoxy-phenyl)-4-methoxy-6-methyl-cyclohexa-1,3-dienecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

: 177036-08-7
(S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine

Guidance literature:: With 4-chloro-phenol; at 180 ℃; for 0.5h;
DOI:10.1021/ja9703741

Reference yield: 16.0%

: 158818-68-9
(S)-2-(2-tert-Butoxycarbonylamino-5-methoxy-phenyl)-4-methoxy-6-methyl-cyclohexa-1,3-dienecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

: 158818-69-0
(S)-7,8-dihydro-2,9-dimethoxy-7-methyl-6(5H)-phenanthridinone

: 177036-08-7
(S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine

Guidance literature:: With 4-chloro-phenol; at 180 ℃; for 0.5h;
DOI:10.1021/ja9703741

Reference yield:

: 158818-67-8
(1R,3R,4S)-p-menth-3-yl(S)-2-hydroxy-4-methoxy-6-methyl-1,3-cyclohexadiene-1-carboxylate, trifluoromethanesulfonate

: 177036-08-7
(S)-7,8-dihydro-6-[(1R,3R,4S)-p-menth-3-yloxy]-2,9-dimethoxy-7-methylphenanthridine

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / Pd(PPh₃)4, CuI, LiCl, 2,6-di-tert-butyl-4-methylphenol / dioxane / 1 h / Heating

2: 16 percent / 4-ClPhOH / 0.5 h / 180 °C

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2,6-di-tert-butyl-4-methyl-phenol; 4-chloro-phenol; lithium chloride; In 1,4-dioxane;
DOI:10.1021/ja9703741