Technology Process of (-)-(6R,9R)-7-oxo-γ-dihydroionol acetate
There total 9 articles about (-)-(6R,9R)-7-oxo-γ-dihydroionol acetate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 6 steps
1: pyridine / 24 h / 20 °C
2: propan-2-ol; xylene / 144 h / Irradiation
3: 0.9 g / KOH / methanol / 20 °C
4: 43 percent / Pseudomonas cepacia lipase PS / various solvent(s) / 96 h / 20 °C
5: 78 percent / pyridine / CH2Cl2 / 24 h / 20 °C
6: 94 percent / Dess-Martin periodinane / CH2Cl2 / 1 h / 20 °C
With
pyridine; potassium hydroxide; Pseudomonas cepacia lipase PS; Dess-Martin periodane;
In
methanol; dichloromethane; isopropyl alcohol; xylene;
DOI:10.1016/j.tetasy.2006.05.024
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 87 percent / tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 15 h / -10 °C
2: pyridine / 24 h / 20 °C
3: propan-2-ol; xylene / 144 h / Irradiation
4: 0.9 g / KOH / methanol / 20 °C
5: 43 percent / Pseudomonas cepacia lipase PS / various solvent(s) / 96 h / 20 °C
6: 78 percent / pyridine / CH2Cl2 / 24 h / 20 °C
7: 94 percent / Dess-Martin periodinane / CH2Cl2 / 1 h / 20 °C
With
pyridine; potassium hydroxide; Pseudomonas cepacia lipase PS; Dess-Martin periodane; acetic acid; tetramethylammonium triacetoxyborohydride;
In
methanol; dichloromethane; isopropyl alcohol; acetonitrile; xylene;
DOI:10.1016/j.tetasy.2006.05.024
