N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine

Base Information

• Chemical Name: N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine
• CAS No.: 1333165-62-0
• Molecular Formula: C₄₆H₄₄N₃P₃
• Molecular Weight: 731.797
• Mol file: 1333165-62-0.mol

Synonyms:N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine

Chemical Property of N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine

There total 1 articles about N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

diphenyl-2-(3-methylindolyl)phosphine (800369-69-1) + diethylphosphoramidous dichloride (1069-08-5) → N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine (1333165-62-0)

Guidance literature:

diphenyl-2-(3-methylindolyl)phosphine; With n-butyllithium; In tetrahydrofuran; at -78 ℃; Inert atmosphere;

diethylphosphoramidous dichloride; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1039/c1dt10360a

Reference yield: 86.0%

chlorobis(cyclooctene)rhodium(I) dimer + N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine (1333165-62-0) + toluene (108-88-3,15644-74-3,16713-13-6) → [RhCl(N,N'-bis(2-(diphenylphosphino)-3-methylindolyl)diethylaminophosphine)]*1.5toluene

Guidance literature:

In tetrahydrofuran; byproducts: C8H14; (N2, Schlenk technique); addn. of rhodium compd. to soln. of phosphine deriv. in THF at room temp., stirring for 1 h; evapn. in vac., washing with hexanes, NMR and MS;

DOI:10.1039/c1dt10360a

Reference yield:

N,N'-bis(2-(diphenylphosphino)-3-(methyl)indolyl)diethylaminophosphine (1333165-62-0) → diphenyl-2-(3-methylindolyl)phosphine (800369-69-1)

Guidance literature:

With lithium aluminium tetrahydride; Inert atmosphere;

DOI:10.1039/c1dt10360a

upstream raw materials:

diphenyl-2-(3-methylindolyl)phosphine

diethylphosphoramidous dichloride

Downstream raw materials:

diphenyl-2-(3-methylindolyl)phosphine