S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate

Base Information

Chemical Name:S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate
CAS No.:352556-31-1
Molecular Formula:C₁₆H₁₆N₂OS₂
Molecular Weight:316.448
Hs Code.:

Synonyms:S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate

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Technology Process of S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate

There total 3 articles about S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 3437-95-4,149762-92-5
2-Iodothiophene

: 352556-23-1
S-[2-(N-prop-2'-ynyl)aminophenyl]-N,N-dimethylthiocarbamate

: 352556-31-1
S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate

Guidance literature:: With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In acetonitrile; at 20 ℃; for 24h;
DOI:10.1021/jo001783+

Reference yield:

: 13511-84-7
S-(2-nitrophenyl)-N,N-dimethylcarbamothioate

: 352556-31-1
S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 89 percent / Fe; water; glacial acetic acid / 8 h / 20 °C

2.1: K₂CO₃ / acetone / 5 h / 20 °C

2.2: 84 percent / acetone / 16 h / Heating

3.1: 90 percent / CuI; Et₃N / PdCl₂(PPh₃)2 / acetonitrile / 24 h / 20 °C

With copper(l) iodide; water; iron; potassium carbonate; acetic acid; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In acetone; acetonitrile;
DOI:10.1021/jo001783+

Reference yield:

: 352556-22-0
S-(2-aminophenyl)-N,N-dimethylthiocarbamate

: 352556-31-1
S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: K₂CO₃ / acetone / 5 h / 20 °C

1.2: 84 percent / acetone / 16 h / Heating

2.1: 90 percent / CuI; Et₃N / PdCl₂(PPh₃)2 / acetonitrile / 24 h / 20 °C

With copper(l) iodide; potassium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In acetone; acetonitrile;
DOI:10.1021/jo001783+